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| ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) Basic information | Reaction |
Product Name: | ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) | Synonyms: | [1,3-bis(2,6-diisopropylphenyl)-2H-imidazol-2-yl]-chloro-palladium;Allylchloro[1,3-bis(2,6-di-i-propylphenyl);imidazol-2-ylidene]palladium(II);ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98;PALLADIUM(II);ALLYLCHLORO[1,3-BIS-(DIISOPROPYLPHENYL)-IMIDAZOLE-2-YLIDENE]PALLADIUM(II);Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium;Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) 98% | CAS: | 478980-03-9 | MF: | C30H41ClN2Pd | MW: | 571.53 | EINECS: | | Product Categories: | Pd;alkylidene complex | Mol File: | 478980-03-9.mol | ![ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) Structure](CAS/GIF/478980-03-9.gif) |
| ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) Chemical Properties |
Melting point | 190°C (dec.) | storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C | form | Powder | color | white | InChI | InChI=1S/Pd/q+2 | InChIKey | MUJIDPITZJWBSW-UHFFFAOYSA-N | SMILES | [Pd+2] |
| ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) Usage And Synthesis |
Reaction |
- Catalyst for the cross-coupling of aryl chlorides with boronic acids.
- Catalyst for the diamination of conjugated dienes and trienes.
- Catalyst for the dehalogenation of aryl chlorides.
- Catalyst for anaerobic alcohol oxidation.
- Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation.
| Chemical Properties | Yellow crystal | Uses |
ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) is used as a catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.
| General Description | Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones. | reaction suitability | core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst |
| ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) Preparation Products And Raw materials |
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