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3-Phenylpropionic acid methyl ester

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3-Phenylpropionic acid methyl ester Basic information
Product Name:3-Phenylpropionic acid methyl ester
Synonyms:Benzenepropanoic acid, methyl ester;benzenepropanoicacid,methylester;beta-Phenylpropionic acid methyl ester;Hydrocinnamic acid, methyl ester;methyl (3-phenyI) propanoate;Methyl 3-phenylpropanoate;Methyl benzenepropanoate;Methyl beta-phenylpropionate
CAS:103-25-3
MF:C10H12O2
MW:164.2
EINECS:203-092-2
Product Categories:Pharmaceutical Intermediates;Aromatic Cinnamic Acids, Esters and Derivatives;Organic acids;103-25-3;11
Mol File:103-25-3.mol
3-Phenylpropionic acid methyl ester Structure
3-Phenylpropionic acid methyl ester Chemical Properties
Melting point 142-145 °C
Boiling point 91-92 °C4 mm Hg(lit.)
density 1.043 g/mL at 25 °C(lit.)
FEMA 2741 | METHYL 3-PHENYLPROPIONATE
refractive index n20/D 1.502(lit.)
Fp 212 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Colourless to Pale Yellow
Odorat 100.00 %. honey fruity wine balsam floral
Odor Typehoney
Water Solubility Soluble in chloroform. Insoluble in water.
JECFA Number643
BRN 1909591
Cosmetics Ingredients FunctionsPERFUMING
InChIKeyRPUSRLKKXPQSGP-UHFFFAOYSA-N
LogP2.26
CAS DataBase Reference103-25-3(CAS DataBase Reference)
NIST Chemistry Reference3-Phenylpropanoic acid methyl ester(103-25-3)
EPA Substance Registry SystemBenzenepropanoic acid, methyl ester (103-25-3)
Safety Information
Safety Statements 24/25
WGK Germany 2
TSCA TSCA listed
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
3-Phenylpropionic acid methyl ester Usage And Synthesis
DescriptionMethyl 3-phenylpropionate has a strong floral-fruity odor. May be prepared by reduction of methyl cinnamate in methanol solution with hydrogen and Ni under pressure.
Chemical PropertiesMethyl-3-phenylpropionate has a strong floral–fruity odor, with honey and wine-like undertones
Chemical PropertiesClear light yellow liquid
OccurrenceReported found in tabasco peppers, grapes, rhubarb, soursop and basil
UsesMethyl 3-phenylpropionate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Phenylpropionic Acid Methyl Ester is an ester derivative of 3-phenylpropionic acid that is sometimes present in fragrance ingredients. It is also used as an application, aromatic intermediate.
DefinitionChEBI: Methyl 3-phenylpropanoate is a methyl ester resulting from the formal condensation of the carboxy group of 3-phenylpropionic acid with methanol. It has a role as a volatile oil component, a flavouring agent and a human metabolite. It is a methyl ester and a member of benzenes. It is functionally related to a 3-phenylpropionic acid.
PreparationBy reduction of methyl cinnamate in methanol solution with hydrogen and Ni under pressure
Aroma threshold valuesAroma characteristics at 1.0%: sweet, rich spicy Ceylon cinnamonlike, balsamic with fruity, resinous and powdery nuances
Taste threshold valuesTaste characteristics at 5 ppm: cinnamon spicy, sweet, balsamic with fruity floral and resinous nuances.
Synthesis Reference(s)Tetrahedron Letters, 30, p. 5293, 1989 DOI: 10.1016/S0040-4039(01)93768-2
Journal of the American Chemical Society, 95, p. 625, 1973 DOI: 10.1021/ja00783a073
Tag:3-Phenylpropionic acid methyl ester(103-25-3) Related Product Information
Ethyl 3-phenylpropionate 3-(3-Trifluoromethyl-phenyl)-prop-2-en-1-ol 4-NITROPHENYL PHENYL SULFIDE Ethanone, 1-(1-naphthalenyl)-, oxiMe (S)-(-)-1-(2-Naphthyl)ethylamine Benzenemethanol, 3-(trifluoromethyl)-, 1-(4-methylbenzenesulfonate) SEVZPXQQXHZTBG-JKSUJKDBSA-N Benzenepropanol, 3-methyl-, 1-(4-methylbenzenesulfonate) 3-(4-TRIFLUOROMETHYL-PHENYL)-PROPAN-1-OL 1-(NAPHTHALEN-1-YL)ETHANONE OXIME 3-(3-Trifluoromethylphenyl)propionic acid SEVZPXQQXHZTBG-HZPDHXFCSA-N 3-(2-TRIFLUOROMETHYL-PHENYL)-PROPAN-1-OL Cinacalcet Impurity D Phenol, 3-(trifluoromethyl)-, 1-(4-methylbenzenesulfonate) 3-Phenylpropyl 4-methylbenzenesulfonate 2-Propenoic acid, 3-[3-(trifluoroMethyl)phenyl]-, Methyl ester Benzenepropanoic acid, 3-Methyl-, Methyl ester