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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

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Products Intro: Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
CAS:14647-23-5
Purity:98% Package:100g~~25kg
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Products Intro: Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
CAS:14647-23-5
Purity:98%(Min,HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg
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Products Intro: Product Name:[1,2-Bis(diphenylphosphino)ethane]dichloronickel(Ⅱ)
CAS:14647-23-5
Purity:99% Package:25KG;5KG;1KG
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Products Intro: Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
CAS:14647-23-5
Purity:98% Package:10MG;50MG;100MG,1G,5G,10G
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Products Intro: Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
CAS:14647-23-5
Purity:99% Package:10kg,25kg,100kg

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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Basic information
Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonyms:DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);[Bis(diphenylphosphino)ethane]dichloronickel;1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II);1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE;1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%
CAS:14647-23-5
MF:C26H24Cl2NiP2
MW:528.02
EINECS:629-489-4
Product Categories:API intermediates;Catalysis and Inorganic Chemistry;Chemical Synthesis;Ni;Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes
Mol File:14647-23-5.mol
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Structure
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties
Melting point 263-265 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Chloroform, Methanol (Sparingly)
form crystal
color orange
Water Solubility insoluble
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:Hygroscopic
InChIInChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
InChIKeyXXECWTBMGGXMKP-UHFFFAOYSA-L
SMILES[Ni+2].C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Cl-].[Cl-]
CAS DataBase Reference14647-23-5(CAS DataBase Reference)
Safety Information
Hazard Codes T,Xn
Risk Statements 45-20/21/22-36/37/38-42/43-40
Safety Statements 53-22-26-36-45-52
WGK Germany 3
TSCA No
HS Code 29319090
Storage Class6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Carc. 1B
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Usage And Synthesis
Chemical PropertiesOrange to red crystalline powder
Usessuzuki reaction
UsesDichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
reaction suitabilitycore: nickel
reagent type: catalyst
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Preparation Products And Raw materials
Raw materialsEthanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Triphenylphosphine-->1,2-Dichloroethane-->Lithium-->1,2-Dibromoethane-->Nickel(II) chloride hexahydrate-->Diphenylphosphine
Tag:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5) Related Product Information
ETHANE Sodium chloride Diphenylphosphine oxide Calcium chloride Ammonium chloride Choline chloride Chlorodiphenylphosphine Hexafluoroethane Diphenylphosphine 1,1'-Bis(diphenylphosphino)ferrocene (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Nickel(II) chloride hexahydrate Nickle chloride Potassium chloride Polyvinyl chloride Methylene Chloride 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE 1,2-Bis(diphenylphosphino)ethane