| Company Name: |
Energy Chemical
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| Tel: |
021-021-58432009 400-005-6266 |
| Email: |
sales8178@energy-chemical.com |
| Products Intro: |
Product Name:Methyl 2-phenylsulfinylacetate
CAS:14090-83-6
Purity:98% Package:5G
|
| Company Name: |
Shanghai Hanhong Scientific Co.,Ltd.
|
| Tel: |
021-54306202 13764082696 |
| Email: |
info@hanhongsci.com |
| Products Intro: |
Product Name:Methyl 2-phenylsulfinylacetate
CAS:14090-83-6
Purity:98% Remarks:B37060
|
| Company Name: |
Chongqing Landtower Pharmaceutical Co., Ltd.
|
| Tel: |
023-68980308 |
| Email: |
business@cqlandtower.com |
| Products Intro: |
Product Name:Modafinil Intermediate
CAS:14090-83-6
Purity:99% HPLC Package:25kg;10kg;5KG;1KG Remarks:API
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
| Products Intro: |
Product Name:Methyl 2-phenylsulfinylacetate
CAS:14090-83-6
Purity:98% Package:5G Remarks:237582-5G
|
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| | METHYL (PHENYLSULFINYL)ACETATE Basic information |
| | METHYL (PHENYLSULFINYL)ACETATE Chemical Properties |
| Melting point | 52-54 °C(lit.) | | Boiling point | 130-131 °C0.5 mm Hg(lit.) | | density | 1.3339 (rough estimate) | | refractive index | 1.5250 (estimate) | | Fp | >230 °F | | form | solid | | BRN | 1953383 | | InChI | 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3 | | InChIKey | JPPXZUDQIXZLIL-UHFFFAOYSA-N | | SMILES | COC(=O)CS(=O)c1ccccc1 |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | Storage Class | 13 - Non Combustible Solids |
| | METHYL (PHENYLSULFINYL)ACETATE Usage And Synthesis |
| Description |
Methyl 2-(Phenylsulfinyl)acetate is a synthetic equivalent of a vinyl organometallic species; undergoes addition/elimination to aldehydes to give
conjugated dienoates or 4-hydroxy (2E)-enoates.
| | Uses | Undergoes condensation reactions with aldehydes to form vinylic sulfoxides.1 | | Uses | Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters. | | General Description | Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides. |
| | METHYL (PHENYLSULFINYL)ACETATE Preparation Products And Raw materials |
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