Allyl phenyl sulfone manufacturers
- Allyl phenyl sulfone
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- $2.00 / 100kg
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2026-04-17
- CAS:16212-05-8
- Min. Order: 1kg
- Purity: 99%
- Supply Ability: 100kg
- Allyl phenyl sulfone
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- $6.60 / 1KG
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2019-12-26
- CAS:16212-05-8
- Min. Order: 500g
- Purity: 98%
- Supply Ability: 1kg, 50kg, 100kg
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| | Allyl phenyl sulfone Basic information |
| | Allyl phenyl sulfone Chemical Properties |
| Boiling point | 110-113 °C/0.5 mmHg (lit.) | | density | 1.189 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.548(lit.) | | Fp | >230 °F | | storage temp. | 2-8°C | | form | clear liquid | | color | Colorless to Orange to Green | | Water Solubility | insol water; sol most organic solvents. | | Sensitive | Light Sensitive | | BRN | 1863561 | | InChI | InChI=1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2 | | InChIKey | KYPIULIVYSQNNT-UHFFFAOYSA-N | | SMILES | C1(S(CC=C)(=O)=O)=CC=CC=C1 | | CAS DataBase Reference | 16212-05-8(CAS DataBase Reference) | | EPA Substance Registry System | Benzene, (2-propenylsulfonyl)- (16212-05-8) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36-37/39 | | WGK Germany | 3 | | RTECS | WR2400000 | | F | 8-10 | | TSCA | TSCA listed | | HazardClass | IRRITANT | | HS Code | 2930909899 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | | Toxicity | mouse,LD50,intravenous,320mg/kg (320mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02689, |
| | Allyl phenyl sulfone Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS TO FAINTLY YELLOW LIQUID | | Uses | Possible usages of allyl phenyl sulfone:
- It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
- It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
- It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.
| | Reactivity Profile | Allyl phenyl sulfone could be used as metalated derivatives serve as ambident nucleophiles; reacts as a 1,1-allylic dianion or 1,1-allylic dipole equivalent[1].
| | Synthesis |
The Preparative Method of Allyl phenyl sulfone: from Allyl Bromide and benzenesulfinate in ethanol according to the original procedure is most straightforward and avoids the use of strong-smelling thiols.
| | References |
1. (a) Magnus, P. D. T 1977, 33, 2019. (b) Block, E. Reactions of Organosulfur Compounds; Academic Press: New York, 1978. (c) Biellmann, J.-F.; Ducep, J.-B. OR 1982, 27, 1.
2. Otto, R. LA 1894, 283, 18; Cope, A. C.; Morrison, D. E.; Field, L. JACS 1950, 72, 59. Vennstra, G. E.; Zwaneburg, B. S 1975, 519.
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| | Allyl phenyl sulfone Preparation Products And Raw materials |
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