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| | 3-Fluorotoluene Basic information |
| | 3-Fluorotoluene Chemical Properties |
| Melting point | -87 °C | | Boiling point | 115 °C(lit.) | | density | 0.991 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.469(lit.) | | Fp | 49 °F | | storage temp. | Store below +30°C. | | form | clear liquid | | color | Colorless to Almost colorless | | Specific Gravity | 0.991 | | Water Solubility | immiscible | | Merck | 14,4180 | | BRN | 1903631 | | Dielectric constant | 5.4199999999999999 | | InChI | 1S/C7H7F/c1-6-3-2-4-7(8)5-6/h2-5H,1H3 | | InChIKey | BTQZKHUEUDPRST-UHFFFAOYSA-N | | SMILES | Cc1cccc(F)c1 | | LogP | 2.75 | | CAS DataBase Reference | 352-70-5(CAS DataBase Reference) | | NIST Chemistry Reference | Benzene, 1-fluoro-3-methyl-(352-70-5) | | EPA Substance Registry System | m-Fluorotoluene (352-70-5) |
| Hazard Codes | F,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 16-26-36-37/39 | | RIDADR | UN 2388 3/PG 2 | | WGK Germany | 2 | | RTECS | XT2578000 | | Hazard Note | Flammable/Irritant | | TSCA | TSCA listed | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29036990 | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Flam. Liq. 2 |
| | 3-Fluorotoluene Usage And Synthesis |
| Chemical Properties | clear colorless to light yellow liquid | | Uses | 3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry. | | Synthesis Reference(s) | Journal of the American Chemical Society, 72, p. 4809, 1950 DOI: 10.1021/ja01166a506 | | General Description | A colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3---may float or sink in water. | | Air & Water Reactions | Highly flammable. | | Reactivity Profile | 3-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned. | | Health Hazard | Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed. | | Purification Methods | Purify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 676, 5 IV 799.] |
| | 3-Fluorotoluene Preparation Products And Raw materials |
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