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3,4-dichloropyridazine

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Products Intro: Product Name:3,4-dichloropyridazine
CAS:1677-80-1
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Products Intro: Product Name:3,4-Dichloropyridazine
CAS:1677-80-1
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Products Intro: Product Name:3,4-Dichloropyridazine
CAS:1677-80-1
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Company Name: Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
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Products Intro: Product Name:3,4-dichloropyridazine
CAS:1677-80-1
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3,4-dichloropyridazine manufacturers

  • 3,4-dichloropyridazine
  • 3,4-dichloropyridazine pictures
  • $0.00 / 1kg
  • 2022-04-22
  • CAS:1677-80-1
  • Min. Order: 0.0001kg
  • Purity: 98%min
  • Supply Ability: 10kgs/month
  • 3,4-dichloropyridazine
  • 3,4-dichloropyridazine pictures
  • $8.80 / 1KG
  • 2019-08-06
  • CAS:1677-80-1
  • Min. Order: 1KG
  • Purity: 97%-99%
  • Supply Ability: 100kg
3,4-dichloropyridazine Basic information
Product Name:3,4-dichloropyridazine
Synonyms:3,4-dichloropyridazine;Pyridazine, 3,4-dichloro-;3,4-dichloropyridazine ISO 9001:2015 REACH
CAS:1677-80-1
MF:C4H2Cl2N2
MW:148.98
EINECS:
Product Categories:
Mol File:1677-80-1.mol
3,4-dichloropyridazine Structure
3,4-dichloropyridazine Chemical Properties
Boiling point 125 °C(Press: 3-4 Torr)
density 1.493±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka-0.89±0.10(Predicted)
Appearancelight gray solid
Safety Information
HS Code 2933998090
MSDS Information
3,4-dichloropyridazine Usage And Synthesis
Synthesis
4-CHLORO-3(2H)-PYRIDAZINONE

1677-79-8

3,4-dichloropyridazine

1677-80-1

General procedure for the synthesis of 3,4-dichloropyridazine from 4-chloro-3-pyridazinone: 4-chloro-3-pyridazinone (25 g, 0.19 mol) was dissolved in acetonitrile (200 ml). Subsequently, phosphoryl chloride (73 g, 0.48 mol) was added to the solution and the reaction mixture was refluxed at 80 °C for 3 hours. After the completion of the reaction was monitored by TLC, the reaction solution was cooled to room temperature and slowly poured into ice water (200 ml). The pH of the mixture was adjusted to 7-8 with sodium bicarbonate and then extracted twice with ethyl acetate (300 ml). The organic phases were combined, washed with saturated brine (400 ml) and dried over anhydrous sodium sulfate. The organic phases were concentrated under reduced pressure and the resulting crude product was purified by column chromatography to give 3,4-dichloropyridazine (18.0 g, 0.12 mol) in about 64% yield.

References[1] Patent: CN104211644, 2016, B. Location in patent: Paragraph 0042-048
3,4-dichloropyridazine Preparation Products And Raw materials
Raw materials4-CHLORO-3(2H)-PYRIDAZINONE-->trichlorophosphate-->Acetonitrile
Preparation Products4-((3-Chloropyridazin-4-yl)oxy)aniline
Tag:3,4-dichloropyridazine(1677-80-1) Related Product Information
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