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1-PHENYLNAPHTHALENE

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CAS:605-02-7
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1-PHENYLNAPHTHALENE Basic information
Synthesis
Product Name:1-PHENYLNAPHTHALENE
Synonyms:1-PHENYLNAPHTHALENE;1-naphthylbenzene;α-Phenylnaphthalene;1-Phenylnaphthalene,96%;1-Phenylnaphthalene 100mg [605-02-7];1-Phenylnaphthalene,97%;1-Phenylnaphthalene 96%;1-Phenylnaphthalene@50 μg/mL in Toluene
CAS:605-02-7
MF:C16H12
MW:204.27
EINECS:210-081-6
Product Categories:Building Blocks;Chemical Synthesis;Arenes;Building Blocks;Organic Building Blocks;Organic Building Blocks
Mol File:605-02-7.mol
1-PHENYLNAPHTHALENE Structure
1-PHENYLNAPHTHALENE Chemical Properties
Melting point 45°C
Boiling point 324-325 °C (lit.)
density 1.085 g/mL at 25 °C (lit.)
refractive index n20/D 1.664(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
color Light orange to Yellow to Green
BRN 1906885
CAS DataBase Reference605-02-7(CAS DataBase Reference)
EPA Substance Registry System1-Phenylnaphthalene (605-02-7)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 2902.90.9000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1-PHENYLNAPHTHALENE Usage And Synthesis
Synthesis	1-PHENYLNAPHTHALENE
To a suspension of potassium phenyltriflfluoroborate (92.3 mg, 0.5 mmol), 1-bromonapthalene (103.5 mg, 0.5 mmol), and K2CO3 (204.5 mg, 1. 5 mmol) in MeOH  (0.75 mL) was added Pd(OAc)2 in methanol (1.25 mL, 2 × 10–3 M) and then the reaction mixture was stirred and heated at reflflux for 2 h. The mixture was cooled to room temperature and diluted with water (10 mL). The aqueous phase was extracted with CH2Cl2 (3 × 4 mL). The combined organic extracts were washed with brine (10 mL) and dried (MgSO4). The crude product was then purifified via chromatography (silica gel) eluting with hexane to deliver 76.1 mg (75%) of 1-phenylnaphthalene. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.
Chemical PropertiesClear colorless to yellow viscous liquid
Synthesis Reference(s)Journal of the American Chemical Society, 101, p. 2246, 1979 DOI: 10.1021/ja00502a074
Organic Syntheses, Coll. Vol. 3, p. 729, 1955
1-PHENYLNAPHTHALENE Preparation Products And Raw materials
Preparation Products1-benzyl-2,3-dihydro-1H-indene-->10-METHYLPHENOTHIAZINE
Tag:1-PHENYLNAPHTHALENE(605-02-7) Related Product Information
DIHYDROXYDIBENZANTHRONE (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (R)-(+)-1,1'-Bi-2-naphthol Diindenoperylene DECACYCLENE 9,10-Diphenylanthracene 1,1'-BINAPHTHYL Rubrene Fluoranthene 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Benzanthrone 3,9-Dibromobenzanthrone 9,10-Bis(4-methoxyphenyl)-2-chloroanthracene Vat Violet 10 9,10-Di(2-naphthyl)anthracene BENZO(B)FLUORANTHENE 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE 3-Bromobenzanthrone

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