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3-Methyl-1-phenyl-2-phospholene 1-oxide

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Company Name: Shanghai Pleikon Chemical Technology Co., Ltd  Gold
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3-Methyl-1-phenyl-2-phospholene 1-oxide manufacturers
3-Methyl-1-phenyl-2-phospholene 1-oxide Basic information
Product Name:3-Methyl-1-phenyl-2-phospholene 1-oxide
Synonyms:3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE;3-METHYL-1-PHENYL-2-PHOSPHOLENE OXIDE;4-METHYL-1-PHENYL-2,3-DIHYDROPHOSPHOL-1-ONE;2,3-DIHYDRO-4-METHYL-1-PHENYL-1H-PHOSPHOLE 1-OXIDE;3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE TECH., 85%;4,5-Dihydro-3-Methyl-1-Phenylphosphole1-Oxide;3-Methyl-1-phenyl-2-phospholene-1-oxide, ca. 98%;4,5-Dihydro-3-Methyl-1-Phenyl-Oxo-Pentylidene Phosphine
CAS:707-61-9
MF:C11H13OP
MW:192.19
EINECS:211-901-5
Product Categories:Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;707-61-9
Mol File:707-61-9.mol
3-Methyl-1-phenyl-2-phospholene 1-oxide Structure
3-Methyl-1-phenyl-2-phospholene 1-oxide Chemical Properties
Melting point 58-62 °C
Boiling point 150 °C/0.15 mmHg (lit.)
density 1.11±0.1 g/cm3(Predicted)
refractive index n20/D 1.5707(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in polar solvents.
form Lumps
color White to cream
Sensitive Hygroscopic
BRN 609223
InChIInChI=1S/C11H13OP/c1-10-7-8-13(12,9-10)11-5-3-2-4-6-11/h2-6,9H,7-8H2,1H3
InChIKeyYMKWWHFRGALXLE-UHFFFAOYSA-N
SMILESP1(=O)(C2=CC=CC=C2)C=C(C)CC1
CAS DataBase Reference707-61-9(CAS DataBase Reference)
EPA Substance Registry System1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide (707-61-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38-40
Safety Statements 26-28-36/37/39-45
WGK Germany 3
RTECS SZ6105100
TSCA TSCA listed
HS Code 2931499090
Storage Class10 - Combustible liquids
Hazard ClassificationsAcute Tox. 4 Oral
Aquatic Chronic 3
Carc. 2
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-Methyl-1-phenyl-2-phospholene 1-oxide Usage And Synthesis
Chemical Propertieswhite to yellow adhering crystals
Uses3-Methyl-1-phenyl-2-phospholene 1-oxide is used as a catalyst for intramolecular aza-wittig cyclization reactions and polymerization reactions. It is a reactant used for the preparation of phospha sugars and their radical bromination derivatives as anticancer agents.
ApplicationCatalyst for:
Intramolecular aza-Wittig cyclization reactions
Polymerization reactions
Reactant for preparation of:
Phospha sugars and their radical bromination derivatives as anticancer agents
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Tag:3-Methyl-1-phenyl-2-phospholene 1-oxide(707-61-9) Related Product Information
3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE,3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE (=3-METHYL-1-PHENYL-1-PHOSPHA-3-CYCLOPENTENE 1-OXIDE) 95+% 3-Methyl-1-phenyl-2-phospholene 1-oxide (METHYL-VINYL-PHOSPHINOYL)-BENZENE (ETHYL-VINYL-PHOSPHINOYL)-BENZENE TRIMETHYLPHOSPHINE OXIDE 1H-Phosphole, 2,3-dihydro-1-phenyl-, 1-oxide