TROPYLIUM TETRAFLUOROBORATE manufacturers
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| | TROPYLIUM TETRAFLUOROBORATE Basic information |
| | TROPYLIUM TETRAFLUOROBORATE Chemical Properties |
| Melting point | ~240 °C (dec.)(lit.) | | storage temp. | Keep Cold | | solubility | Soluble in hot methanol. | | form | powder to crystal | | color | White to Light yellow to Light orange | | Sensitive | Moisture Sensitive | | BRN | 3574512 | | InChI | InChI=1S/C7H7.BF4/c1-2-4-6-7-5-3-1;2-1(3,4)5/h1-7H;/q+1;-1 | | InChIKey | SQVQHTIKOZVGLR-UHFFFAOYSA-N | | SMILES | [B-](F)(F)(F)F.C1C=C[CH+]C=CC=1 | | CAS DataBase Reference | 27081-10-3(CAS DataBase Reference) | | EPA Substance Registry System | Cycloheptatrienylium, tetrafluoroborate(1-) (27081-10-3) |
| Hazard Codes | Xi,C | | Risk Statements | 37/38-34 | | Safety Statements | 22-28-45-36/37/39-26 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 3 | | F | 10-21 | | Hazard Note | Irritant/Keep Cold/Moisture Sensitive | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29029090 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | TROPYLIUM TETRAFLUOROBORATE Usage And Synthesis |
| Chemical Properties | off-white to beige powder | | Uses | Reactant or reagent involved in:• ;Retro-Buchner reactions for synthesis of arylcyclopropanes1• ;Desymmetrization for access to homocalystegine analogs2 or aminocycloheptitols3• ;α-Cyanation of imines4• ;Stereoselective α-alkylation of aldehydes with stable carbocations5• ;Oxidative C-H activation of aliphatic aldehydes6• ;Electrochemical Redox transformations7 | | Uses | Tropylium Tetrafluoroborate (CAS# 27081-10-3) can be used as an electrolytic solution for electrochemical devices, as well as for protective coatings for selenium electrophotographic plates. | | Uses | Reactant or reagent involved in:
- Retro-Buchner reactions for synthesis of arylcyclopropanes
- Desymmetrization for access to homocalystegine analogs or aminocycloheptitols
- α-Cyanation of imines
- Stereoselective α-alkylation of aldehydes with stable carbocations
- Oxidative C-H activation of aliphatic aldehydes
- Electrochemical Redox transformations
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| | TROPYLIUM TETRAFLUOROBORATE Preparation Products And Raw materials |
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