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| | Lithium bis(oxalate)borate Basic information |
| Product Name: | Lithium bis(oxalate)borate | | Synonyms: | lithium bis(oxalate)borate;CHEMLYTE BO M1;CHEMLYTE BO MX;LITHIUM BIS (OXALATE) BORATE(LiBOB);Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium (1:1), (T-4)-;Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium, (T-4)-;Lithium bis(oxalate)borate LiBOB Lithium bis(ethanedioato)borate;LithiuM 2,3,7,8-tetraoxo-1,4,6,9-tetraoxa-5-boraspiro[4.4]nonan-5-uide | | CAS: | 244761-29-3 | | MF: | C4BLiO8 | | MW: | 193.79 | | EINECS: | 456-990-3 | | Product Categories: | | | Mol File: | 244761-29-3.mol |  |
| | Lithium bis(oxalate)borate Chemical Properties |
| Melting point | >300°C (lit.) | | vapor pressure | 0.004Pa at 20℃ | | storage temp. | Inert atmosphere,Room Temperature | | form | powder or crystals | | Appearance | White Powder | | Water Solubility | 1015g/L at 20℃ | | InChI | InChI=1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1 | | InChIKey | NVQAYVUCVASGDK-UHFFFAOYSA-N | | SMILES | O=C1C([O-][B+3]2([O-]C(=O)C(=O)[O-]2)[O-]1)=O.[Li+] | | LogP | 0 at 20℃ | | EPA Substance Registry System | Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | TSCA | TSCA listed | | HS Code | 29319090 | | Storage Class | 13 - Non Combustible Solids | | Hazard Classifications | Acute Tox. 4 Oral
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| | Lithium bis(oxalate)borate Usage And Synthesis |
| Uses | Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc. | | Uses | LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode. | | General Description | This product has been enhanced for energy efficiency. | | Flammability and Explosibility | Non flammable | | Synthesis |
Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].
| | References | [1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.
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| | Lithium bis(oxalate)borate Preparation Products And Raw materials |
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