N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE

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N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE manufacturers

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE Basic information

Product Name:	N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE
Synonyms:	ALPHA,ALPHA'-DIETHYLENEDINITRILODI-O-CRESOL;A,A'-(ETHYLENEDINITRILO)DI-O-CRESOL;2,2'-ETHYLENEBIS(NITRILOMETHYLIDENE)DIPHENOL;2-[((2-[(2-HYDROXYBENZYLIDENE)AMINO]ETHYL)IMINO)METHYL]PHENOL;N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE, F OR FLUORESCENCE;N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE, 9 8%;bis-(SALICYLIDENE)-ETHYLENEDIAMINE REAGENT;disalicylaldehyde ethylenediamine
CAS:	94-93-9
MF:	C16H16N2O2
MW:	268.31
EINECS:	202-376-3
Product Categories:	Indazoles
Mol File:	94-93-9.mol

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE Chemical Properties

Melting point	127-128 °C(lit.)
Boiling point	411.48°C (rough estimate)
density	1.1028 (rough estimate)
refractive index	1.6240 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	chloroform: 0.1 g/mL, clear
pka	12.59±0.50(Predicted)
form	crystal
color	yellow
Water Solubility	water: insoluble(lit.)
Merck	14,8322
BRN	535296
InChI	1S/C16H16N2O2/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/b17-11+,18-12+
InChIKey	VEUMANXWQDHAJV-JYFOCSDGSA-N
SMILES	Oc1ccccc1\C=N\CC\N=C\c2ccccc2O
CAS DataBase Reference	94-93-9(CAS DataBase Reference)
EPA Substance Registry System	Phenol, 2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis- (94-93-9)

Safety Information

MSDS Information

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE Usage And Synthesis

Chemical Properties	YELLOW FINE CRYSTALLINE POWDER
Uses	In histochemistry to detect antigens.
Uses	N,N′-Bis(salicylidene)ethylenediamine (salen) immobilized on surfactant-coated alumina has been used as complexing agent for on-line preconcentration of copper and lead by flow injection-flame atomic absorption spectrometry (FI-AAS).
Definition	A green fluorescent compound.
General Description	N,N′-Bis(salicylidene)ethylenediamine (salen) reacts with ferric chloride in acetone solution to yield the complex (Fe salen Cl).
Synthesis	90-02-8 107-15-3 94-93-9 c) General steps for synthesizing VO (salen) catalysts: Step 1: Synthesis of salen ligand Salicylaldehyde (7.307 g, 6.38 mL, 0.0598 mol) was mixed with ethylenediamine (1.798 g, 2 mL, 0.0299 mol) in anhydrous ethanol and the reaction was stirred for 1 hour at room temperature. After completion of the reaction, the resulting precipitate was collected by filtration, washed with ethanol and subsequently dried in air. 7.25 g of salen ligand was obtained in 90% yield.
References	[1] New Journal of Chemistry, 2014, vol. 38, # 11, p. 5411 - 5414 [2] Green Chemistry, 2014, vol. 16, # 3, p. 1374 - 1382 [3] Patent: WO2005/70911, 2005, A1. Location in patent: Page/Page column 35-36 [4] Catalysis Today, 2012, vol. 192, # 1, p. 44 - 55 [5] Journal of Materials Chemistry C, 2015, vol. 3, # 42, p. 11099 - 11110

N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE Preparation Products And Raw materials

Raw materials	Water-->Salicylaldehyde-->Ethylenediamine
Preparation Products	Ethylenediamine-N,N'-bis((2-hydroxyphenyl)acetic acid)

Tag:N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE(94-93-9) Related Product Information

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]ALUMINUM (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE SALCOMINE N,N'-Bis(salicylidene)ethylenediamine copper salt Cresol Ethylenediamine Salicylaldehyde o-Cresol Cresol

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