ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE

(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE

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(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Suppliers list
Company Name: Shenzhen Nexconn Pharmatechs Ltd
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Products Intro: Product Name:(1Z,5Z)-cycloocta-1,5-diene,(2S,5S)-1-[2-[(2S,5S)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane,rhodium,tetrafluoroborate
CAS:213343-64-7
Purity:0.98 Package:1KG;10KG;50KG
Company Name: Shaanxi Dideu Medichem Co. Ltd
Tel: +86-029-89586680 +86-18192503167
Email: 1026@dideu.com
Products Intro: Product Name:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
CAS:213343-64-7
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001：2015 REACH Approved Manufacturer
Company Name: Aladdin Scientific
Tel:
Email: tp@aladdinsci.com
Products Intro: Product Name:(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:213343-64-7
Purity:>=98% Package:$105.9/100mg;Bulk package Remarks:98%
Company Name: Aladdin Scientific
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Email: tp@aladdinsci.com
Products Intro: Product Name:(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:213343-64-7
Purity:>=98%(S,S)-Et-DUPHOS-Rh Package:$360.9/100mg;$1538.9/500mg;$4995.9/2g;Bulk package Remarks:98%(S,S)-Et-DUPHOS-Rh
Company Name: Shanghai Hanhong Scientific Co., Ltd.
Tel: +undefined17612118332
Email: Lucky@hanhonggroup.com
Products Intro: Product Name:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
CAS:213343-64-7
Package:5KG;1KG;100kg;1000kg
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Basic information
Reactions
Product Name:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
Synonyms:(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluroborate;(+)-Bisdiethylphospholanobenzenecyclooctadienerhod;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Et-DUPHOS-Rh;1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluroborate;(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Et-DUPHOS-Rh;1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
CAS:213343-64-7
MF:C30H46BF4P2Rh
MW:658.35
EINECS:
Product Categories:organometallic complex
Mol File:213343-64-7.mol
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Structure
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Chemical Properties
form Powder
color Orange to red to brown
Sensitive air sensitive
InChIKeyDSYBEQKPSKLNMC-ZCTOJWETSA-N
SMILES[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC[C@H]2CC[C@H](CC)P2c3ccccc3P4[C@@H](CC)CC[C@@H]4CC
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
HS Code 28439000
Storage Class11 - Combustible Solids
MSDS Information
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Usage And Synthesis
Reactions
  1. Ligand used in asymmetric hydrogenation of 2-methylenesuccinamic acid.
  2. Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-aminomethylacrylates. 
Reactions of 213343-64-7
Chemical PropertiesDark orange-red solid
Uses(S,S)-Et-DUPHOS-Rh is a catalyst in the asymmetric preparation of B precursor of cryptophycin, and in the synthesis of constrained phenylalanine analogs.
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenation
  • Preparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization steps
  • Enantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomers
  • Preparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitors
  • Stereoselective preparation of triply isotope-labeled Ser, Cys, and Ala
  • Preparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylates
  • Asymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine
(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE Preparation Products And Raw materials
Tag:(+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE(213343-64-7) Related Product Information
Benzene (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE (+)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE 1,2-BIS(PHOSPHINO)BENZENE (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE