(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene

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(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Suppliers list
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(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Basic information
Reaction
Product Name:(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene
Synonyms:(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (S,S,S)-(-)-Ph-SKP;(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97%;(-)-1,13-BIS(DIPHENYL)PHOSPHINO-(5AS,8AS,14AS)-5A,6,7,8,8A,9-HEXAHYDRO-5H-[1]BENZOPYRANO[3,2-D]XANTHENE,97%(S,S,S)-(-)-PH-SKP;Phosphine, 1,1'-[(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-diphenyl-;1,13-bis(diphenylphosphaneyl)-5a,6,7,8,8a,9-hexahydro-5H-chromeno[3,2-d]xanthene;1,1'-[(5aS,8aS,14aS)-5a,6,7,8,8a,9-Hexahydro-5H-[1]benzopyrano[3,2-d]xanthene-1,13-diyl]bis[1,1-diphenyl-phosphine
CAS:1439556-82-7
MF:C44H38O2P2
MW:660.72
EINECS:
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Mol File:1439556-82-7.mol
(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Structure
(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Chemical Properties
Melting point 101-103°C
alpha -113° (c 1.00, CHCl3)
storage temp. 2-8°C, stored under nitrogen
form solid
color white
Sensitive air sensitive
Safety Information
MSDS Information
(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Usage And Synthesis
Reaction
  1. Efficient ligand for the Au(I)-catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
  2. Palladium-catalyzed asymmetric allylic amination of Morita-Baylis-Hillman adducts. Exceptionally high efficiency and new mechanism.
Reactions of 1439556-82-7
Uses(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene is used as a catalyst in reactions. Used in preparation of chiral a-Methylene-b-lactam compounds as antitumor agents.
(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene Preparation Products And Raw materials
Tag:(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene(1439556-82-7) Related Product Information