3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline

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3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline Basic information
Product Name:3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline
Synonyms:3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline;Li-Quinoline Ligand;2,5-Dimethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline;2H-Pyrano[2,3-b]quinoline, 3,4-dihydro-2,5-dimethyl-
CAS:151657-37-3
MF:C14H15NO
MW:213.27
EINECS:
Product Categories:
Mol File:151657-37-3.mol
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline Structure
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline Chemical Properties
Melting point 143-147°C
Boiling point 367.9±21.0 °C(Predicted)
density 1.117±0.06 g/cm3(Predicted)
pka4.26±0.40(Predicted)
form solid
InChI1S/C14H15NO/c1-9-7-8-12-10(2)11-5-3-4-6-13(11)15-14(12)16-9/h3-6,9H,7-8H2,1-2H3
InChIKeyZENOEMLZOZWVRD-UHFFFAOYSA-N
SMILESCC1=C2C(OC(C)CC2)=NC3=C1C=CC=C3
Safety Information
WGK Germany 3
Storage Class11 - Combustible Solids
MSDS Information
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline Usage And Synthesis
UsesLigand can be used in the presence of Pd(TFA)2 (Aldrich 299685) to promote C-H activation of β-Aryl-α-amino acids. This product has shown to be optimal with a 2:1 ratio of Ligand:Pd Source for several examples reported by the Yu group.
reaction suitabilityreagent type: catalyst
reagent type: ligand
reaction type: C-H Activation
3,4-Dihydro-2,5-dimethyl-2H-pyrano[2,3-b]quinoline Preparation Products And Raw materials
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