7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride

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7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride Basic information
Product Name:7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride
Synonyms:2,3-DIHYDRO-7-METHOXY-1H-INDEN-1-AMINE HYDROCHLORIDE;7-METHOXY-2,3-DIHYDRO-1H-INDEN-1-AMINE HCL;7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride
CAS:1187160-18-4
MF:C10H14ClNO
MW:199.67726
EINECS:
Product Categories:
Mol File:1187160-18-4.mol
7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride Structure
7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride Chemical Properties
storage temp. Sealed in dry,Room Temperature
AppearanceWhite to off-white Solid
Safety Information
MSDS Information
7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride Usage And Synthesis
Synthesis
1H-Inden-1-one, 2,3-dihydro-7-methoxy-, oxime

908108-58-7

7-METHOXY-2,3-DIHYDRO-1H-INDEN-1-AMINE HYDROCHLORIDE

1187160-18-4

7-Methoxyindan-1-one oxime (2.92 g, 16 mmol) was dissolved in acetic acid (150 mL) and the hydrogenation reaction was carried out using an H-cube hydrogenation reactor under the following conditions set at a flow rate of 1 mL/min, a temperature of 80 °C, a pressure of 100 bar, and a catalyst of 10% Pd/C. Upon completion of the reaction, the solvent in the reaction mixture was removed by evaporation and the residue was dissolved in methanol, followed by the addition of 1 equiv. of hydrochloric acid in methanol. The solvent was evaporated again and the resulting residue was ground with ether to give 7-methoxy-1-aminoindan hydrochloride (2.38 g, 12 mmol, 75% yield). Electrospray mass spectrometry (ESMS) showed m/z 147 ([M + H]+).

References[1] Patent: WO2010/71846, 2010, A2. Location in patent: Page/Page column 160
7-Methoxy-2,3-dihydro-1H-inden-1-amine hydrochloride Preparation Products And Raw materials
Raw materials1H-Inden-1-one, 2,3-dihydro-7-methoxy-, oxime-->Hydrogen-->Water-->Acetic acid-->Methanol-->Hydrochloric acid
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