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Heptaethylene Glycol Monomethyl Ether

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CAS:4437-01-8
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CAS:4437-01-8
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Heptaethylene Glycol Monomethyl Ether manufacturers

  • mPEG7-OH
  • mPEG7-OH pictures
  • $0.00 / 1g
  • 2026-01-28
  • CAS:4437-01-8
  • Min. Order: 1g
  • Purity: 98%
  • Supply Ability: 300kg
  • m-PEG7-alcohol
  • m-PEG7-alcohol pictures
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  • 2026-01-05
  • CAS:4437-01-8
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  • Purity: 96.02%
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Heptaethylene Glycol Monomethyl Ether Basic information
Product Name:Heptaethylene Glycol Monomethyl Ether
Synonyms:Heptaetheylene glycol methyl ether;mPEG7;HEPTAETHYLENE GLYCOL MONOMETHYL ETHER;Methoxyheptaethylene glycol, Monomethoxy-PEG (n=7);MPEG7-OH;Heptaetheylene glycol MonoMethyl ether;2,5,8,11,14,17,20-Heptaoxadocosan-22-ol;3,6,9,12,15,18,21-heptaoxadocosan-1-ol
CAS:4437-01-8
MF:C15H32O8
MW:340.41
EINECS:
Product Categories:Chemical Biology;Chemical Synthesis;High Oligomer Purity PEG;PEGylation;Monofunctional Ethylene Glycols;Ethylene Glycols & Monofunctional Ethylene Glycols;PEG-COOH;peg
Mol File:4437-01-8.mol
Heptaethylene Glycol Monomethyl Ether Structure
Heptaethylene Glycol Monomethyl Ether Chemical Properties
Boiling point 150 °C(Press: 0.005 Torr)
density 1.09
refractive index 1.4540-1.4580
storage temp. -20°C
form clear liquid
pka14.36±0.10(Predicted)
color Colorless to Light yellow to Light orange
InChIInChI=1S/C15H32O8/c1-17-4-5-19-8-9-21-12-13-23-15-14-22-11-10-20-7-6-18-3-2-16/h16H,2-15H2,1H3
InChIKeyAGWKUHGLWHMYTG-UHFFFAOYSA-N
SMILESC(O)COCCOCCOCCOCCOCCOCCOC
CAS DataBase Reference4437-01-8(CAS DataBase Reference)
Safety Information
WGK Germany 3
HS Code 29094990
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
Heptaethylene Glycol Monomethyl Ether Usage And Synthesis
Descriptionm-PEG7-alcohol is a PEG linker containing a hydroxyl group. The hydroxyl group enables further derivatization or replacement with other reactive functional groups. The hydrophilic PEG spacer increases solubility in aqueous media.
UsesApplications may include: bioconjugation, drug delivery, PEG hydrogel, crosslinker, and surface functionalization
Definition The presence of heptaethylene glycol monomethyl ether (HGME) as a process impurity and degradation impurity in the final purified form of Benzonatate is a determining factor in establishing the safety, identity, strength, purity, and quality of the drug substance. Owing to the cutaneous toxicity of HGME in the BNZ drug substance, a suitable and selective analysis method is required for its quantitation[1].
reaction suitabilityreagent type: cross-linking reagent
Synthesis
Bis[2-(2-hydroxyethoxy)ethyl] ether

112-60-7

Methyl-PEG3-MS

74654-05-0

Heptaethylene Glycol Monomethyl Ether

4437-01-8

A 60% NaH dispersion in mineral oil was added in batches to a stirred solution of triacetylene glycol (35.7 mmol) in anhydrous DMF (25.7 mL) under nitrogen protection, and the mixture was stirred for 1 hour at room temperature. Subsequently, a solution of 2-(2-(2-methoxyethoxy)ethoxy)ethyl methanesulfonate (23.36 mmol) in anhydrous DMF (4 mL) was added in a single addition to the resulting salt, and stirring was continued for 3.5 hours at room temperature. The progress of the reaction was monitored by thin layer chromatography (TLC with 12% unfolding agent ratio). Upon completion of the reaction, the reaction mixture was diluted with an equal volume of 1N HCl, extracted with ethyl acetate (2 x 20 mL) and the organic phase discarded. The aqueous phase was extracted and post-treated to give heptaglycol monomethyl ether in 82-84% yield.

IC 50PEGs
References[1] Lakshmi Narasimha Rao Katakam, Vishnu Murthy Marisetti, Santhosh Kumar Ettaboina. “Development and validation of LC–MS method for the determination of heptaethylene glycol monomethyl ether in benzonatate bulk drugs.” Biomedical Chromatography 35 7 (2021).
Tag:Heptaethylene Glycol Monomethyl Ether(4437-01-8) Related Product Information
1-{2-[2-(2-{2-[2-(2-Bromo-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-2-methoxy-ethane mPEG6-CH2COOH 2,5,8,11,14,17,20-Heptaoxadocosane-22-thiol m-PEG7-aldehyde Polyethylene Glycol Monocetyl Ether POLYETHYLENE GLYCOL MONO-4-NONYLPHENYL ETHER NONAETHYLENE GLYCOL MONODODECYL ETHER C10 E8 C14E8 Dicyclohexano-24-crown-8 C12E8 HEPTAETHYLENE GLYCOL MONODODECYL ETHER POLY(ETHYLENE GLYCOL) (N) MONOMETHACRYLATE Polyoxyethylene lauryl ether C16 E8 Benzonatate Polyoxyethylene stearate Heptaethylene glycol

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