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| | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Basic information |
| Product Name: | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE | | Synonyms: | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE;4,4-Dimethyl-2-phenyl-2-oxazoline 96%;4,4-Dimethyl-2-phenyl-4,5-dihydro-1,3-oxazole;Oxazole, 4,5-dihydro-4,4-dimethyl-2-phenyl-;4,4-Dimethyl-2-phenyl-2-oxazoline;4,4-dimethyl-2-phenyl-2-azoleline | | CAS: | 19312-06-2 | | MF: | C11H13NO | | MW: | 175.23 | | EINECS: | | | Product Categories: | Building Blocks;Heterocyclic Building Blocks;Oxazolines/Oxazolidines | | Mol File: | 19312-06-2.mol |  |
| | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Chemical Properties |
| Melting point | 20-24 °C(lit.) | | Boiling point | 124 °C20 mm Hg(lit.) | | density | 1.025 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.5322(lit.) | | Fp | 217 °F | | storage temp. | 2-8°C, stored under nitrogen | | pka | 4.82±0.70(Predicted) | | Appearance | Colorless to off-white <20°C Solid,>24°C Liquid | | BRN | 132225 | | InChI | 1S/C11H13NO/c1-11(2)8-13-10(12-11)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3 | | InChIKey | UGNSMKDDFAUGFT-UHFFFAOYSA-N | | SMILES | CC1(C)COC(=N1)c2ccccc2 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Usage And Synthesis |
| Uses | 4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring. | | Synthesis Reference(s) | Journal of the American Chemical Society, 82, p. 2032, 1960 DOI: 10.1021/ja01493a045 Tetrahedron Letters, 27, p. 5269, 1986 DOI: 10.1016/S0040-4039(00)85187-4 | | General Description | 4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids. 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX2(ox)2] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX2] (X = Cl, Br, I).Except ZnI2, which does not form an isolable complex due to steric reasons. |
| | 4,4-DIMETHYL-2-PHENYL-2-OXAZOLINE Preparation Products And Raw materials |
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