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| | 3,5-Dibromobenzoic acid Basic information |
| Product Name: | 3,5-Dibromobenzoic acid | | Synonyms: | Benzoic acid, 3,5-dibromo-;RARECHEM AL BO 0773;3,5-dibromo-benzoicaci;3,5-DIBROMOBENZOIC ACID;BUTTPARK 99\57-19;3,5-DibroMobenzoic Acid, 97+%;3,5-DibromobenzoicAcid>;1,3-Dibromobenzoicacid | | CAS: | 618-58-6 | | MF: | C7H4Br2O2 | | MW: | 279.91 | | EINECS: | | | Product Categories: | OLED;Benzoic acid series;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Benzoic acid;Acids & Esters;Bromine Compounds;Building Blocks for Dendrimers;Functional Materials;C7;Carbonyl Compounds;Carboxylic Acids;bc0001 | | Mol File: | 618-58-6.mol |  |
| | 3,5-Dibromobenzoic acid Chemical Properties |
| Melting point | 218-220 °C (lit.) | | Boiling point | 355.2±32.0 °C(Predicted) | | density | 1.9661 (rough estimate) | | refractive index | 1.4970 (estimate) | | storage temp. | Sealed in dry,Room Temperature | | solubility | Very faint turbidity in methanol. | | pka | 3.42±0.10(Predicted) | | form | powder to crystal | | color | White to Light yellow | | BRN | 1940691 | | InChI | InChI=1S/C7H4Br2O2/c8-5-1-4(7(10)11)2-6(9)3-5/h1-3H,(H,10,11) | | InChIKey | SFTFNJZWZHASAQ-UHFFFAOYSA-N | | SMILES | C(O)(=O)C1=CC(Br)=CC(Br)=C1 | | CAS DataBase Reference | 618-58-6(CAS DataBase Reference) | | NIST Chemistry Reference | 3,5-Dibromobenzoic acid(618-58-6) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | WGK Germany | 3 | | RTECS | DG6290010 | | HazardClass | IRRITANT | | HS Code | 29163990 |
| | 3,5-Dibromobenzoic acid Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powder | | Uses | 3,5-Dibromobenzoic acid may be used for the syntheses (+)-menthyl 3,5-dibromobenzoate, di-tert-butyl 4-[2-(tert-butoxycarbonyl)ethyl]-4-(3,5-dibromobenzamido)heptanedioate2, (L)-methyl 2-(3,5-dibromobenzamido)-3-phenylpropanoate. | | General Description | 3,5-Dibromobenzoic acid is 3,5-dibromo-substituted benzoic acid. | | Synthesis | 3,5-Dibromobenzoic acid was synthesized from anthranilic acid by bromination, diazotization and additional reactions derived. The bromination reaction is carried out at about 20°C. After the reaction, the crystals are filtered, washed with hot water to remove anthranilic acid and hydrochloric acid, and recrystallized with acetic acid to obtain o-amino-3,5-dibromobenzoic acid; then use sodium nitrite to carry out diazotization in hydrochloric acid at about 0°C, then add the diazonium salt into ethanol containing calcium sulfate at 60-70°C in batches. After the addition is complete, continue stirring for 10 minutes, filter to obtain the crude product, and recrystallize with ethanol to obtain the finished product. |
| | 3,5-Dibromobenzoic acid Preparation Products And Raw materials |
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