1-Methyl 2-aminoterephthalate

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1-Methyl 2-aminoterephthalate Basic information
Product Name:1-Methyl 2-aminoterephthalate
Synonyms:2-AMINOTEREPHTHALIC ACID 1-METHYL ESTER;2-AMINOTEREPHTHALIC ACID METHYL ESTER;2-AMINOTEREPHTHALIC ACID MONOMETHYL ESTER;1-METHYL 2-AMINOTEREPHTHALATE;2-Aminoterephthalate acid 1-Methyl ester;3-Amino-4-carbomethoxybenzoic Acid 3-Amino-4-methoxycarbonylbenzoic Acid 2-Aminoterephthalic Acid 1-Methyl Ester;3-AMINO-4-METHOXYCARBONYLBENZOIC ACID;3-AMINO-4-CARBOMETHOXYBENZOIC ACID
CAS:60728-41-8
MF:C9H9NO4
MW:195.17
EINECS:
Product Categories:Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Phthalic Acids, Esters and Derivatives;C8 to C9;Carbonyl Compounds;Esters
Mol File:60728-41-8.mol
1-Methyl 2-aminoterephthalate Structure
1-Methyl 2-aminoterephthalate Chemical Properties
Melting point 217-220 °C (lit.)
Boiling point 394.9±32.0 °C(Predicted)
density 1.373±0.06 g/cm3(Predicted)
storage temp. 2-8°C, protect from light
solubility concentrated acid: soluble (HCl)(lit.)
form powder to crystal
pka3.93±0.10(Predicted)
color White to Yellow to Green
InChI1S/C9H9NO4/c1-14-9(13)6-3-2-5(8(11)12)4-7(6)10/h2-4H,10H2,1H3,(H,11,12)
InChIKeyQKOKLMFCKLEFDV-UHFFFAOYSA-N
SMILESCOC(=O)c1ccc(cc1N)C(O)=O
CAS DataBase Reference60728-41-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29224999
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
1-Methyl 2-aminoterephthalate Usage And Synthesis
Uses1-Methyl-2-aminoterephthalate may be used in the following syntheses:
  • triarylphosphine
  • methyl 4-(hydroxymethyl-2-iodobenzoate
  • 1-methyl-2-diphenylphosphinoterepthalate
General Description1-Methyl-2-aminoterephthalate (3-Amino-4-carbomethoxybenzoic acid, 3-Amino-4-methoxycarbonylbenzoic acid) is the 1-methyl ester of 2-aminoterephthalic acid.
1-Methyl 2-aminoterephthalate Preparation Products And Raw materials
Preparation ProductsC. I. Pigment Yellow 182
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