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2-METHYL-1-PROPENYLMAGNESIUM BROMIDE

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CAS:8614-36-7
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Products Intro: Product Name:2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
CAS:38614-36-7
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CAS:38614-36-7
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Products Intro: Product Name:2-Methyl-1-propenylmagnesium bromide
CAS:38614-36-7
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2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Basic information
Product Name:2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
Synonyms:2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF;2-Methyl-1-propenylmagnesium bromide, 0.5M solution in THF, AcroSeal;(2-Methylprop-1-en-1-yl)MagnesiuM broMide;2-Methyl-1-propenylmagnesium bromide 0.5M solution in THF;2-Methyl-1-propenylMagnesiuM broMide, 0.5M solution in THF, J&KSeal;(beta,beta-Dimethylvinyl)magnesium bromide;1-Bromomagnesio-2-methyl-1-propene;2,2-Dimethylvinylmagnesium bromide
CAS:38614-36-7
MF:C4H7BrMg
MW:159.31
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Organometallic Reagents;Alkenyl;Grignard Reagents;Organometallic Reagents;Grignard Reagent
Mol File:38614-36-7.mol
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Structure
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Chemical Properties
density 0.952 g/mL at 25 °C
Fp 5 °F
form Solution
color Yellow to dark orange
InChI1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChIKeyBKVIQODYSREJQH-UHFFFAOYSA-M
SMILESC\C(C)=C\[Mg]Br
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14/15-19-20/21/22-34-37-40-36/37/38-15
Safety Statements 16-26-27-36/37/39-45-43-36/37
RIDADR UN 3399 4.3/PG 2
WGK Germany 3
HS Code 29319090
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsAcute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 2
MSDS Information
ProviderLanguage
SigmaAldrich English
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesYellow to dark orange liquid
UsesUsed in a synthesis of (2S,3S)-3′-fluoroisoleucine.
Uses2-Methyl-1-propenylmagnesium bromide can be used in a study of a palladium-catalyzed coupling with aryl tosylates.
Uses2-Methyl-1-propenylmagnesium bromide(0.5M in THF) is a reagent used in many chemical reactions such as in the preparation of biaryls, alkylarenes, alkenylarenes, alkynylalkenones via nucleophilic addition.Used in the study of palladium-catalyzed coupling with aryl tosylates.
reaction suitabilityreaction type: Grignard Reaction
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation ProductsCYCLOHEPTANE-->2,5-Dimethyl-2,4-hexadiene
Tag:2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(38614-36-7) Related Product Information
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