ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Phosphine ligand >(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers list
Company Name: XINXIANG RUNYU MATERIAL CO., LTD.
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Products Intro: Product Name:(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl
CAS:167709-31-1
Purity:99%+ Package:100G|1000G|10000G
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Products Intro: Product Name:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS:167709-31-1
Purity:98% Package:1KG;1USD
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Products Intro: Product Name:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS:167709-31-1
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Products Intro: Product Name:(S)-(-)-2,2''-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl
CAS:167709-31-1
Purity:97% Package:$70.9/100mg;$264.9/500mg;$898.9/2g;Bulk package Remarks:97%
Company Name: Chongqing Chemdad Co., Ltd
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Products Intro: Product Name:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS:167709-31-1
Purity:0.98 Package:1kg，2kg，5kg，10kg，25kg

(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information
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Product Name:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine];(S)-3,5-t-Bu-MeOBIPHEP, SL-A121-2, (S)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]- 6,6'-dimethoxy-1,1'-biphenyl;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99%;Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)phenyl]-
CAS:167709-31-1
MF:C70H96O2P2
MW:1031.46
EINECS:
Product Categories:Chiral Phosphine;MeOBIPHEP Series
Mol File:167709-31-1.mol
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Structure
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties
Boiling point 856.5±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color white
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis
Reactions
  1. Pd-catalyzed enantioselective Heck reaction.
  2. Used in enantioselective lactam synthesis via Pd-catalyzed intramolecular allylic alkylation.
  3. Used in enantioselective Au-catalyzed polycyclization reactions. 
Reactions of 167709-31-1
Chemical PropertiesWhite powder
Uses(S)-3,5-t-Bu-MeOBIPHEP can be used as a ligand in the stereoselective preparation of allenoates via palladium-catalyzed asymmetric carbonylation of propargylic carbonates. It can also be used in the C-C coupling reactions.
General Descriptionsold in collaboration with Solvias AG
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Tag:(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%(167709-31-1) Related Product Information
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chloro[(R)-(-)5,5μ-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4μ-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny