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4-Nitrophenylhydrazine

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Products Intro: Product Name:4-Nitrophenylhydrazine
CAS:100-16-3
Purity:99.99% Package:25kg/drum
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CAS:100-16-3
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Products Intro: Product Name:4-Nitrophenylhydrazine
CAS:100-16-3
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Products Intro: Product Name:4-Nitrophenylhydrazine
CAS:100-16-3
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Products Intro: CAS:100-16-3
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4-Nitrophenylhydrazine Basic information
Product Name:4-Nitrophenylhydrazine
Synonyms:1-(4-NITROPHENYL)HYDRAZINE;(4-nitrophenyl)-hydrazin;(p-nitrophenyl)-hydrazin;Hydrazine, (4-nitrophenyl)-;Hydrazine, (p-nitrophenyl)-;Hydrazine,(4-nitrophenyl)-;p-Hydrazinonitrobenzene;p-Nitrophenylhydrazide
CAS:100-16-3
MF:C6H7N3O2
MW:153.14
EINECS:202-824-8
Product Categories:Phenylhydrazine;HydrazinesDerivatization Reagents;Derivatization Reagents HPLC;Nitrogen Compounds;Organic Building Blocks;UV-VIS;Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes
Mol File:100-16-3.mol
4-Nitrophenylhydrazine Structure
4-Nitrophenylhydrazine Chemical Properties
Melting point 156 °C (dec.)(lit.)
Boiling point 276.04°C (rough estimate)
density 1.00
refractive index 1.6910 (estimate)
storage temp. Explosives area
pka3.81±0.20(Predicted)
color Orange-red leaflets or needles
Water Solubility soluble in hot water
Merck 14,6624
BRN 608107
CAS DataBase Reference100-16-3(CAS DataBase Reference)
NIST Chemistry ReferenceP-nitrophenyl hydrazine(100-16-3)
EPA Substance Registry SystemHydrazine, (4-nitrophenyl)- (100-16-3)
Safety Information
Hazard Codes F,Xn
Risk Statements 5-11-22-36/37/38-43-21/22
Safety Statements 16-26-36/37/39-37/39-36
RIDADR UN 3376 4.1/PG 1
WGK Germany 3
RTECS MV8225000
4.6
Hazard Note Flammable/Harmful
TSCA TSCA listed
HazardClass 4.1
PackingGroup I
HS Code 29280000
Toxicitymmo-sat 2 mmol/L AEMIDF 44,801,82
MSDS Information
ProviderLanguage
4-Nitrophenylhydrazine English
SigmaAldrich English
ACROS English
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4-Nitrophenylhydrazine Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesAnalytical reagent (aldehydes, ketones).
Uses4-Nitrophenylhydrazine is a nitro substituted aryl hydrazine with potential anticancer activity. Irritant.
DefinitionChEBI: A member of the class of phenylhydrazines that is phenylhydrazine substituted at the 4-position by a nitro group.
General Description4-Nitrophenylhydrazine is a orange-red leaflet or needles wetted with water. 4-Nitrophenylhydrazine will emit toxic oxides of nitrogen when heated to decomposition. 4-Nitrophenylhydrazine is slightly heavier than water and insoluble in water. 4-Nitrophenylhydrazine may be irritating to skin, eyes and mucous membranes. 4-Nitrophenylhydrazine may be toxic by ingestion. 4-Nitrophenylhydrazine may be explosive and sensitive to friction in the dry state. 4-Nitrophenylhydrazine is used as a reagent for ketones and aliphatic aldehydes.
Reactivity Profile4-NITROPHENYLHYDRAZINE is a powerful explosive. 4-Nitrophenylhydrazine can SELF-IGNITE in the presence of contaminants. Auto-ignition temperature may vary for 4-nitrophenylhydrazine similar to that of hydrazine which has an autoignition of as low as 74oC in contact with iron rust. Dangerous fire hazard or severe explosion can occur when exposed to heat, flame or oxidizing agents. Severe explosion may also occur by chemical reaction with alkali metals; BaO; CaO; K; Na; NH3; Cl2; chromates; CuO; Cu++ salts; F2; H2O2; iron rust; metallic oxides; PbO2;Ni; Ni(ClO4)2; HNO3; N2O; O2; liquid O2; K2Cr2O7; Na2Cr2O7; tetryl; zinc diamide; Zn(C2H5)2. Dangerous; when heated to decomposition 4-Nitrophenylhydrazine emits highly toxic nitrogen compounds; may explode by heat or chemical reaction. (Sax and Lewis, 1987) under Hydrazine p. 538-539.
Health HazardSome are toxic and may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Safety ProfilePoison by intraperitoneal route.Mutation data reported. When heated to decomposition itemits toxic fumes of NOx. See also NITROCOMPOUNDS OF AROMATIC HYDROCARBONS
Purification MethodsCrystallise the hydrazine from EtOH. The hydrochloride has m 212o(dec) (from EtOH, also m 202-203o dec). [Beilstein 15 III 331, 15 IV 317.]
Tag:4-Nitrophenylhydrazine(100-16-3) Related Product Information
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