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Trimethoxyphenylsilane

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Trimethoxyphenylsilane Basic information
Product Name:Trimethoxyphenylsilane
Synonyms:Benzene, (triMethoxysilyl)-;Trimethoxyphenylsilane >=94%;Trimethoxyphenylsilane deposition grade, 98%;A 153;CP0330;phenyltrimethoxy-silan;Silane, phenyltrimethoxy-;trimethoxyphenyl-silan
CAS:2996-92-1
MF:C9H14O3Si
MW:198.29
EINECS:221-066-9
Product Categories:silane;organosilicon compounds;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Trialkoxysilanes;Phenyl Silanes
Mol File:2996-92-1.mol
Trimethoxyphenylsilane Structure
Trimethoxyphenylsilane Chemical Properties
Melting point -25°C
Boiling point 233 °C(lit.)
density 1.062 g/mL at 25 °C(lit.)
vapor pressure 0-12790Pa at 20-25℃
refractive index n20/D 1.468(lit.)
Fp 99 °F
storage temp. Inert atmosphere,2-8°C
form liquid
color colorless
Specific Gravity1.064
OdorMild odor
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 2937896
InChI1S/C9H14O3Si/c1-10-13(11-2,12-3)9-7-5-4-6-8-9/h4-8H,1-3H3
InChIKeyZNOCGWVLWPVKAO-UHFFFAOYSA-N
SMILESCO[Si](OC)(OC)c1ccccc1
LogP-0.74-2 at 22℃
CAS DataBase Reference2996-92-1(CAS DataBase Reference)
NIST Chemistry ReferenceSilane, trimethoxyphenyl-(2996-92-1)
EPA Substance Registry SystemSilane, trimethoxyphenyl- (2996-92-1)
Safety Information
Hazard Codes T,Xi,Xn
Risk Statements 10-36/37/38-68/20/21/22-20/21/22-14
Safety Statements 7-16-26-36/37-45-37/39-36
RIDADR UN 1992 3/PG 3
WGK Germany 3
RTECS VV5252000
10-21
TSCA TSCA listed
HazardClass 3.2
PackingGroup III
HS Code 29319090
Storage Class3 - Flammable liquids
Hazard ClassificationsAcute Tox. 4 Oral
Flam. Liq. 3
Skin Corr. 1B
STOT RE 2
STOT SE 2
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Trimethoxyphenylsilane Usage And Synthesis
Chemical PropertiesColorless transparent liquid
UsesAn organosilicate compound for nanoelectronics and material science research.
UsesPhenyltrimethoxysilane is used for nanoelectronics and material science research. It is used as crosslinking agent for silicone resin and to produce polymer organic silicon compound.
UsesTMPS can also be used in the preparation of polytrimethoxyphenylsilane (PTMS) that facilitates the removal of graphene after chemical vapor deposition (CVD). Molecularly imprinted sol gels can be synthesized by using TMPS for the fabrication of localized surface plasmon resonance (LSPR).
General DescriptionTrimethoxyphenylsilane (TMPS) is an organotrialkoxysilane that is used as a functional monomer in the sol-gel processing.
Flammability and ExplosibilityFlammable
Purification MethodsFractionate it through an efficient column but note that it forms an azeotrope with MeOH which is a likely impurity. [Kantor J Am Chem Soc 75 2712 1953 Beilstein 16 IV 1556.]
AdvantagesThe polymer molecule generated from phenyltrimethoxysilane contains a rigid hydrophobic group benzene ring and a water-permeable and breathable silica chain. It has surface activity and weather resistance and can be used as an additive in the coating industry, phenyl silica. Introducing chain links can significantly improve thermoelasticity, mechanical properties, and resin adhesion. Therefore, phenyl silicone resin is widely used as high-temperature-resistant electrical insulating paint, high-temperature-resistant coatings, and molding packaging materials.
Toxics Screening LevelThe initial threshold screening level (ITSL) for phenyltrimethoxysilane is 60 μg/m3 based on an annual averaging time.
Tag:Trimethoxyphenylsilane(2996-92-1) Related Product Information
Trimethoxysilane Trimethoxysilylpropanethiol Methyltriethoxysilane 3-Aminopropyltrimethoxysilane Isobutyltrimethoxysilane Vinyltrimethoxysilane 3-Chloropropyltrimethoxysilane Diphenyldiethoxysilane Phenyltriethoxysilane Trimethoxypropylsilane Dodecyltrimethoxysilane Triethoxyoctylsilane Methyltrimethoxysilane SILANE COUPLING AGENT Chlorodimethylphenylsilane Ethyl silicate Phenylsilane Phenyltris(trimethylsiloxy)silane

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