Molybdenyl acetylacetonate

Molybdenyl acetylacetonate Suppliers list

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Molybdenyl acetylacetonate Basic information

Product Name:	Molybdenyl acetylacetonate
Synonyms:	Molybdenum, dioxobis(2,4-pentanedionato-O,O')-;Molybdenum-di(oxybisacetylacetonate);Molybdenyl VI oxide bis(2,4-pentanedionate );Molybdenyl acetylacetonate, 97% 50GR;Molybdenum (VI) dioxide bis(acetylacetonate), 97+%;Acetylacetone Molybdenum(VI)dioxy Salt Bis(acetylacetonato)dioxomolybdenum(VI) Molybdenum(VI)dioxy Acetylacetonate;Molybdenyl (IV) oxide bis(2,4-pentanedionate);Bis(acetylacetonato)dioxomolybdenum(Ⅵ)
CAS:	17524-05-9
MF:	C10H14MoO6
MW:	326.15
EINECS:	241-522-0
Product Categories:	Catalysis and Inorganic Chemistry;Chemical Synthesis;Molybdenum;Mo (Molybdenum) Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:	17524-05-9.mol

Molybdenyl acetylacetonate Chemical Properties

Melting point	184 °C (dec.) (lit.)
density	1,64 g/cm³
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	Pale yellow
Specific Gravity	1.640
Water Solubility	8.52 g/100 mL (20 ºC)
Sensitive	Air Sensitive
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
Exposure limits	ACGIH: TWA 0.5 mg/m3 NIOSH: IDLH 1000 mg/m3
InChI	InChI=1S/2C5H8O2.Mo.2O/c21-4(6)3-5(2)7;;;/h23,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;
InChIKey	SKMUJBBRXZPAJY-VGKOASNMSA-L
SMILES	[Mo](=O)(=O)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C
NIST Chemistry Reference	Molybdenyl acetylacetonate(17524-05-9)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	20/21/22-36/37/38-40
Safety Statements	23-26-36/37/39-45-24/25
WGK Germany	3
TSCA	No
HS Code	29144000
Storage Class	11 - Combustible Solids
Hazard Classifications	Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Carc. 2 Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

MSDS Information

Provider	Language
Bis(acetylacetonato)dioxomolybdenum(VI)	English
ACROS	English
SigmaAldrich	English
ALFA	English

Molybdenyl acetylacetonate Usage And Synthesis

Preparation	Molybdenyl acetylacetonate can be prepared by reacting molybdenum trioxide and acetylacetonate in ammonia water and then acidifying with nitric acid; molybdenyl acetylacetonate can also be prepared by reacting diethoxy molybdenum dioxide and acetylacetonate in toluene.
Chemical Properties	light yellow, greyish green to yellow-brown
Uses	Forms a functional model compound for the study of oxotransferase molybdenum enzymes. Mild catalyst for the deprotection of acetals in high yield. Catalyzes high yield oxidation of secondary alcohols to ketones with sodium percarbonate and phase-transfer catalyst.
reaction suitability	core: molybdenum reagent type: catalyst

Molybdenyl acetylacetonate Preparation Products And Raw materials

Tag:Molybdenyl acetylacetonate(17524-05-9) Related Product Information

Bis(acetylacetonato)cobalt Iron oxide Molybdenum Zinc(II) acetylacetonate Chromium(III) acetylacetonate Zinc oxide ETHYLENE OXIDE Aluminum acetylacetonate Cobaltic acetylacetonate Nickel(II) acetylacetonate ZIRCONIUM(IV) ACETYLACETONATE Cupric acetylacetonate Magnesium oxide Calcium acetylacetonate Acetylacetone VANADIUM(III) ACETYLACETONATE Ruthenium acetylacetonate Ferric acetylacetonate