2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE manufacturers
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| | 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Basic information |
| Product Name: | 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE | | Synonyms: | 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxa-phosphol;2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE;2-Chloro-4,4,5,5-tetraMethyl-1,3,2-dioxaphospholane 95%;1,3,2-Dioxaphospholane, 2-chloro-4,4,5,5-tetramethyl- | | CAS: | 14812-59-0 | | MF: | C6H12ClO2P | | MW: | 182.59 | | EINECS: | | | Product Categories: | Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors | | Mol File: | 14812-59-0.mol |  |
| | 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Chemical Properties |
| Boiling point | 81.5-82 °C13 mm Hg(lit.) | | density | 1.149 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.471(lit.) | | Fp | >230 °F | | InChI | InChI=1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3 | | InChIKey | WGPCXYWWBFBNSS-UHFFFAOYSA-N | | SMILES | O1C(C)(C)C(C)(C)OP1Cl |
| Hazard Codes | C | | Risk Statements | 14-34 | | Safety Statements | 22-26-27-36/37/39-45 | | RIDADR | UN 3265 8/PG 2 | | WGK Germany | 3 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Eye Dam. 1
Skin Corr. 1B |
| | 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Usage And Synthesis |
| Description | 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane is an organic reagent commonly used in chemical and experimental research as a reagent for the phosphorylation of alcohols and heteroatoms for the formation of glycosyl donors and ligands, and in analytical studies of derivatised lignin samples. It is also used as a catalyst in CuO/TiO2 catalysed lignin oxidation studies. | | Chemical Properties | 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane is an organic reagent in the physical state of a solid. Molecular weight: 182.59, Density: 1.149 g/cm3, Boiling point: 81.5-82° C (lit.) at 13 mmHg, Flash point: 113 °C, Refractive index: n20/D 1.471 (lit.), Store at 10°C-25°C, keep dry, under inert gas nitrogen. | | Uses | 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane (TMDP) can be used:
- As a reagent for the phosphitylation of alcohols and heteroatomic nucleophiles, resulting in the formation of useful glycosyl donors and ligands.
- As a phosphitylation reagent to derivatize lignin samples for 31P NMR analysis.
| | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
| | 2-CHLORO-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAPHOSPHOLANE Preparation Products And Raw materials |
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