|
|
| | COPPER TRIFLUOROMETHANETHIOL Basic information | | Uses |
| | COPPER TRIFLUOROMETHANETHIOL Chemical Properties |
| Melting point | >160°C (dec.) | | storage temp. | 0-10°C | | solubility | Acetonitrile (Sparingly) | | form | Solid | | color | Light Beige to Light Brown | | Stability: | Air Sensitive, Hygroscopic, Moisture Sensitive |
| Hazard Codes | T | | Risk Statements | 20/21/22 | | Safety Statements | 22-36/37/39 | | Hazard Note | Toxic | | HS Code | 2930200090 |
| | COPPER TRIFLUOROMETHANETHIOL Usage And Synthesis |
| Uses | Copper(I) Trifluoromethanethiolate is useful for the synthesis of (trifluoromethylthiomethyl/trifluoromethylsulfonylmethyl)dihydropyrazoles. | | Uses | Copper(I) Trifluoromethanethiolate is useful for the synthesis of (trifluoromethylthiomethyl/trifluoromethylsulfonylmethyl)dihydropyrazoles. | | Synthesis |
Trifluoromethylthiocopper can be prepared using two different procedures (eq 1). Heating of finely divided Copper powder with bis(trifluoromethylthio)mercury neat at 80-100 °C until the appearance of an orange color persists, and then heating for 30 min at 150 °C, gives the desired product upon cooling, ether extraction, and evaporation. Stirring copper powder and bis(trifluoromethyl) disulfide in DMF for 1 h gives trifluoromethylthiocopper as its 1:1 DMF adduct. Additionally, this reagent has been prepared by metal exchange of trifluoromethylthiosilver with Copper(I) Bromide.
| | Precautions |
Stable for several months when stored over phosphorus pentoxide at ambient temperature. Use in a fume hood.
|
| | COPPER TRIFLUOROMETHANETHIOL Preparation Products And Raw materials |
|
|
Tag:COPPER TRIFLUOROMETHANETHIOL(3872-23-9)
Related Product Information
|
|
1,1,1,2,3,3,3-Heptafluoropropane
Copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine
COPPER TRIFLUOROMETHANETHIOL
(3,3,3-TRIFLUOROPROPYL)TRIMETHOXYSILANE
(Trifluoromethylsulfonyloxy) copper(I)
Iron(III) trifluoromethanesulfonate
EUROPIUM TRIFLUOROMETHANESULFONATE
trifluoromethanesulfonic acid 2-nitronaphthalen-1-yl ester
3,3,3-trifluoropropyl trifluoromethanesulfonate
Silver(I) trifluoromethanethiolate
DIBUTYLBORON TRIFLUOROMETHANESULFONATE
TIN(II) TRIFLUOROMETHANESULFONATE
Trifluoromethanesulfonic anhydride
CUPROUS TRIFLUOROMETHANESULFONATE TOLUENE COMPLEX
SAMARIUM(III) TRIFLUOROMETHANESULFONATE
GALLIUM(III) FLUORIDE
|