Methyl (E)-3-pentenoate

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Methyl (E)-3-pentenoate Basic information
Product Name:Methyl (E)-3-pentenoate
Synonyms:(E)-CH3CH=CHCH2C(O)OCH3;METHYL 3-PENTENOATE;methyl (e)-3-pentenoate;METHYL TRANS-3-PENTENOATE;METHYL TRANS-PENTENOIC ACID;3-PENTENOIC ACID METHYL ESTER;METHYL (E)-PENT-3-ENOATE;METHYL TRANS-3-PENTENOAT
CAS:20515-19-9
MF:C6H10O2
MW:114.14
EINECS:628-216-6
Product Categories:C6 to C7;Carbonyl Compounds;Esters;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:20515-19-9.mol
Methyl (E)-3-pentenoate Structure
Methyl (E)-3-pentenoate Chemical Properties
Melting point 37.22°C (estimate)
Boiling point 55-56 °C/20 mmHg (lit.)
density 0.93 g/mL at 25 °C (lit.)
refractive index n20/D 1.421(lit.)
Fp 75 °F
form clear liquid
color Colorless to Light yellow
InChI1S/C6H10O2/c1-3-4-5-6(7)8-2/h3-4H,5H2,1-2H3/b4-3+
InChIKeyKJALUUCEMMPKAC-ONEGZZNKSA-N
SMILES[H]\C(C)=C(\[H])CC(=O)OC
CAS DataBase Reference20515-19-9(CAS DataBase Reference)
NIST Chemistry Reference(E)-Pent-3-enoic acid methyl ester(20515-19-9)
Safety Information
Risk Statements 10-22
Safety Statements 16
RIDADR UN 3272 3/PG 3
WGK Germany 3
F 10
HS Code 2916.19.3000
HazardClass 3.2
PackingGroup III
Storage Class3 - Flammable liquids
Hazard ClassificationsFlam. Liq. 3
MSDS Information
ProviderLanguage
SigmaAldrich English
Methyl (E)-3-pentenoate Usage And Synthesis
UsesMethyl trans-3-pentenoate may be used for the total synthesis of phytochemicals (-)-grandinolide and (-)-sapranthin.
General DescriptionMethyl trans-3-pentenoate is an ester. Ring-closing metathesis (RCM) of methyl trans-3-pentenoate using silica- and monolith supported Grubbs-Herrmann-type catalysts has been reported. The 1,3-dipolar cycloaddition of with C-ethoxycarbonyl nitrone to form isoxazolidines has been studied.
Methyl (E)-3-pentenoate Preparation Products And Raw materials
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