(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Suppliers list

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Products Intro:	Product Name:(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE CAS:155830-69-6 Purity:0.97 Package:1g;USD\|2g;USD\|5g;USD\|10g;USD\|50g;USD\|100g;USD

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Products Intro:	Product Name:(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE CAS:155830-69-6 Purity:98%99% Package:100G;1KG;5KG;10KG;25KG;50KG;100KG

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Products Intro:	Product Name:(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE CAS:155830-69-6 Purity:99% Package:25KG;5KG;1KG

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE manufacturers

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Basic information

Product Name:	(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
Synonyms:	(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]-ethyl-di-tert-butylphosphine, Manufactured by Solvias AG;(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine >=97%;-2-(Diphenylphosphino);ferrocenyl]ethyldi-tert-butylphosphine;"Josiphos SL-J002-1/ (R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine";Josiphos SL-J002;Josiphos SL-J002-1 / (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-di-T-butylphosph
CAS:	155830-69-6
MF:	C32H40FeP2
MW:	542.45
EINECS:
Product Categories:	Chiral Phosphine;Ferrocene Series;Josiphos Series;organophosphine ligand
Mol File:	155830-69-6.mol

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties

Melting point	218-220°C (dec.)
alpha	-412° ±15° (c 0.5, CHCl3)
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform, Methanol
form	Powder
color	Orange
InChI	InChI=1/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/s3
InChIKey	STAGMXYQPGLLTD-MGIYCFTINA-N
SMILES	P(C1=CC=CC=C1)(C1=CC=CC=C1)[C]1[CH][CH][CH][C]1[C@@H](C)P(C(C)(C)C)C(C)(C)C.[CH]1[CH][CH][CH][CH]1.[Fe] \|&1:18,r,^1:13,14,15,16,17,29,30,31,32,33\|

Safety Information

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Usage And Synthesis

Reaction	Ligand for Palladium-catalyzed amination of aryl halides Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties	Orange powder
Uses	It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General Description	(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-^tBu) is a chiral ferrocenyl diphosphine ligand.

(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Tag:(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE(155830-69-6) Related Product Information

(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI(3,5-DIMETHYLPHENYL)PHOSPHINE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE (R)-(S)-JOSIPHOS 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE T-BUTYLPHOSPHINE (R)-1-[(S)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL]-ETHYLDI-TERT-BUTYLPHOSPHINE (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Di-tert-butylphosphine (S)-1-[(1R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE TRIISOPROPYLPHOSPHINE Ferrocene DI-T-BUTYL(I-PROPYL)PHOSPHINE (S)-1-[(RP)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine TERT-BUTYLDIISOPROPYLPHOSPHINE (R)-1-[(S)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE (R)-1-[(S)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE

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