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| | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Basic information |
| Product Name: | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE | | Synonyms: | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE;2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE;[2-(Chloromethyl)-2-propenyl]trimethylsilane;2-(Trimethylsilylmethyl)-2-propenyl chloride;2-(Trimethylsilylmethyl)-3-chloro-1-propene;2-Methylene-3-chloropropyltrimethylsilane;2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride | | CAS: | 18388-03-9 | | MF: | C7H15ClSi | | MW: | 162.73 | | EINECS: | | | Product Categories: | | | Mol File: | 18388-03-9.mol |  |
| | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Chemical Properties |
| Boiling point | 162-163 °C/768 mmHg (lit.) | | density | 0.899 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.453(lit.) | | Fp | 110 °F | | storage temp. | 2-8°C | | solubility | Chloroform, Methanol (Slightly) | | form | Oil | | Specific Gravity | 0.899 | | color | Clear Colourless | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 1747038 | | Stability: | Moisture Sensitive | | InChI | 1S/C7H15ClSi/c1-7(5-8)6-9(2,3)4/h1,5-6H2,2-4H3 | | InChIKey | CQXWCEVXNRHUSQ-UHFFFAOYSA-N | | SMILES | C[Si](C)(C)CC(=C)CCl |
| Hazard Codes | Xi | | Risk Statements | 10-36/37/38 | | Safety Statements | 26-36 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | TSCA | No | | HazardClass | 3.2 | | PackingGroup | III | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Usage And Synthesis |
| Uses | 2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones. |
| | 2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Preparation Products And Raw materials |
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