| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
| Company Name: |
LaaJoo |
| Tel: |
021-60702684 18516024827 |
| Email: |
huang.jiayi@sinocompound.com |
|
| | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Basic information | | Reaction |
| Product Name: | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene | | Synonyms: | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene;(S,R(p),S(SPO)-1-Phenylphosphinoyl)-2-[1-(tert-butylphosphino)ethyl]-ferrocene;(S, R(p), S(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos;(R,S(p), R(SPO)-1-Phenylphosphinoyl)-2-[1-(t-butylphosphino)ethyl]ferrocene, Min. 97% JoSPOphos;(2S)-1-[(1S)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-[(S)-phenylphosphinyl]ferrocene (acc to CAS);(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene >=97%;(R,S(P),R(SPO)-1-PHENYLPHOSPHINOYL)-2-[1-(DI-T-BUTYLPHOSPHINO)ETHYL]FERROCENE,MIN.97%JOSPOPHOS;cyclopenta-1,3-diene:(Z)-[2-[(1S)-1-ditert-butylphosphanylethyl]cyclopenta-2,4-dien-1-ylidene]-oxido-phenylphosphanium:iron(2+) | | CAS: | 1221746-66-2 | | MF: | C26H30FeOP2 | | MW: | 476.32 | | EINECS: | | | Product Categories: | JoSPOphos Series;Chiral Phosphine;Ferrocene Series | | Mol File: | 1221746-66-2.mol | ![(RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Structure](CAS/20180906/GIF/1221746-66-2.gif) |
| | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Chemical Properties |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | color | orange | | Stability: | store cold | | InChI | 1S/C21H31OP2.C5H5.Fe/c1-16(24(20(2,3)4)21(5,6)7)18-14-11-15-19(18)23(22)17-12-9-8-10-13-17;1-2-4-5-3-1;/h8-16,23H,1-7H3;1-5H;/t16-;;/m0../s1 | | InChIKey | ZRFUSACJLNCGTO-SQKCAUCHSA-N | | SMILES | [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2[P@H](=O)c3ccccc3)P(C(C)(C)C)C(C)(C)C |
| WGK Germany | 3 | | HS Code | 29319090 | | Storage Class | 11 - Combustible Solids |
| | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Usage And Synthesis |
| Reaction |
- Ligands used for the rhodium-catalyzed asymmetric hydrogenation of functionalized alkenes, α- and β- ketoesters.
- Ligand for rhodium -catalyzed enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles.
- Ligand for rhodium-catalyzed highly regio- and enantioselective addition of pyrazoles to terminal allenes.
| | Chemical Properties | Yellow powder | | General Description | sold in collaboration with Solvias AG |
| | (RP)-1-[(S)-1-(Di-tert-butylphosphino)ethyl]-2-[(S)-phenylphosphinoyl]ferrocene Preparation Products And Raw materials |
|