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| | BORANE-TRIPHENYLPHOSPHINE COMPLEX Basic information |
| | BORANE-TRIPHENYLPHOSPHINE COMPLEX Chemical Properties |
| Melting point | 189-191 °C (lit.) | | storage temp. | Refrigerator | | form | Powder | | color | White | | Sensitive | Air & Moisture Sensitive | | Stability: | Stable. Incompatible with acids, oxidizing agents, acid chlorides, alcohols. May decompose on exposure to air and moisture. | | InChI | 1S/C18H15P.BH3/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;1H3 | | InChIKey | CHVBILDTVBDARQ-UHFFFAOYSA-N | | SMILES | B.c1ccc(cc1)P(c2ccccc2)c3ccccc3 | | CAS DataBase Reference | 2049-55-0(CAS DataBase Reference) |
| RIDADR | UN3396 | | WGK Germany | 3 | | HazardClass | 4.3 | | PackingGroup | II | | HS Code | 29319019 | | Storage Class | 11 - Combustible Solids |
| | BORANE-TRIPHENYLPHOSPHINE COMPLEX Usage And Synthesis |
| Chemical Properties | white crystals with an unpleasant smell | | Uses | Reactant for:
- C-P cross coupling with aryl iodides
- Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
- Catalyst-free alcoholysis to deprotect phosphane-boranes
- Undergoing heterolytic activation
- Deprotection via reactions with resin-supported amines
- Insertion of overcrowded silylene into hydroboranes
| | reaction suitability | reagent type: reductant |
| | BORANE-TRIPHENYLPHOSPHINE COMPLEX Preparation Products And Raw materials |
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