Bis(N,N'-di-t-butylacetamidinato)nickel(II)

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Bis(N,N'-di-t-butylacetamidinato)nickel(II) Basic information
Uses Reaction
Product Name:Bis(N,N'-di-t-butylacetamidinato)nickel(II)
Synonyms:Bis(N,N'-di-t-butylacetaMidinato)nickel(II), (99.999%-Ni) PURATREM;Bis(N,N'-di-t-butylacetamidinato)nickel;(99.999%-Ni) PURATREM;Bis(N,N'-di-t-butylacetamidinato)nickel(Ni(t-Bu-Me-AMD)2);Bis(N,N'-di-t-butylacetamidinato)nickel(II);Bis(N,N''-di-t-butylacetamidinato)nickel(II),;Bis(N,N'-di-t-butylacetamidinato)nickel(Ni(t-Bu-Me-AMD)2);Bis(N,N'-di-t-butylacetamidinato)nickel(II)
CAS:940895-79-4
MF:C20H42N4Ni
MW:397.28
EINECS:
Product Categories:
Mol File:940895-79-4.mol
Bis(N,N'-di-t-butylacetamidinato)nickel(II) Structure
Bis(N,N'-di-t-butylacetamidinato)nickel(II) Chemical Properties
Melting point 95-96°C
form crystal
color dark, purple-black
Sensitive air sensitive, moisture sensitive
Safety Information
MSDS Information
Bis(N,N'-di-t-butylacetamidinato)nickel(II) Usage And Synthesis
UsesCVD/ALD precursor for the preparation of nickel nitride (NiNx) films.
CVD/ALD precursor for the preparation of nickel sulfide (NiSx) films co-deposited by H2S.
Reaction
  1. Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
  2. Catalyst precursor, with AgSbF6, for the asymmetric carbonylene reaction.
  3. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.
Reactions of 940895-79-4
Bis(N,N'-di-t-butylacetamidinato)nickel(II) Preparation Products And Raw materials
Tag:Bis(N,N'-di-t-butylacetamidinato)nickel(II)(940895-79-4) Related Product Information
(N,N'-Di-sec-butylacetamidinato)copper(I) Bis(N,N'-di-I-propylacetamidinato) cobalt(II) bis(n,n'-di-tert-butylacetamidinato)iron(ii) Bis(N,N'-diMethylpiperazine)tetra[copper(I) iodide], 98% MOF