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| | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine Basic information | | Reaction |
| Product Name: | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine | | Synonyms: | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine;(R)-SPIROPAP;N-[(1'R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-2-PYRIDINEMETHANAMINE;(R)-DTB-SpiroPAP;N-[(1'R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-2-pyridinemethanamine,99%e.e.;(R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(PYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE,MIN.98%(>99%EE)(R)-DTB-SPIROPAP;(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>;99% ee) (R)-DTB-SpiroPAP | | CAS: | 1298133-21-7 | | MF: | C51H63N2P | | MW: | 735.03 | | EINECS: | | | Product Categories: | Chiral Phosphine;Chiral Spiro Ligand | | Mol File: | 1298133-21-7.mol |  |
| | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine Chemical Properties |
| Melting point | 172-174°C | | alpha | +172° (c 0.5, CH2Cl2) | | Boiling point | 751.9±60.0 °C(Predicted) | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | pka | 4.80±0.12(Predicted) | | form | solid | | color | white | | Sensitive | air sensitive |
| | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine Usage And Synthesis |
| Reaction | Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.
|
| | (R)-N-(Pyridin-2-ylmethyl)-7′-di(
3,5-di-tert-butylphenyl)phosphin
o-1,1′-spirobiindanyl-7-amine Preparation Products And Raw materials |
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