2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

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2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate Basic information
Product Name:2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate
Synonyms:2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate;2-Chloro-6-(trimethylsilyl)phenyl triflate 95%;2-Chloro-6-(trimethylsilyl)phenyl triflate;Garg 3-chlorobenzyne precursor;Methanesulfonic acid, 1,1,1-trifluoro-, 2-chloro-6-(trimethylsilyl)phenyl ester
CAS:1449472-59-6
MF:C10H12ClF3O3SSi
MW:332.8
EINECS:
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Mol File:1449472-59-6.mol
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate Structure
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate Chemical Properties
Boiling point 319.3±42.0 °C(Predicted)
density 1.36±0.1 g/cm3(Predicted)
storage temp. 2-8°C
form liquid
InChI1S/C10H12ClF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3
InChIKeyQFWUIGWOSVHZMC-UHFFFAOYSA-N
SMILESClC1=C(OS(=O)(C(F)(F)F)=O)C([Si](C)(C)C)=CC=C1
Safety Information
WGK Germany WGK 3
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate Usage And Synthesis
Uses2-Chloro-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate is used in the preparation of aryne precursors for selective generation of haloarynes.
UsesChlorosilyltriflate has been shown to be a useful precursor for the generation of a chlorobenzyne intermediate. The chlorobenzyne intermediate can be generated in the presence of Cesium or Potassium Fluoride and can be trapped with various dipolariphiles.
2-chloro-6-(trimethylsilyl)phenyl trifluoromethanesulfonate Preparation Products And Raw materials
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