Josiphos SL-J009-1 Pd G3 manufacturers
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| | Josiphos SL-J009-1 Pd G3 Basic information | | Reaction |
| Product Name: | Josiphos SL-J009-1 Pd G3 | | Synonyms: | JOSIPHOS Palladacycle Gen. 3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3];Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3];BRUNO PALLADACYCLE;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3;cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron;(SP-4-3)-[2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][(2R)-1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino-κP]ethyl]-2-(dicyclohexylphosphino)ferrocene](methanesulfonato-κO)palladium (ACI) | | CAS: | 1702311-34-9 | | MF: | C45H66FeNO3P2PdS10*- | | MW: | 925.287962 | | EINECS: | | | Product Categories: | | | Mol File: | 1702311-34-9.mol |  |
| | Josiphos SL-J009-1 Pd G3 Chemical Properties |
| Melting point | 180-186 °C | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | solid | | color | red-orange | | InChIKey | VXSQFQJKYCLYAK-DHOIFHORSA-N | | SMILES | NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe] |
| WGK Germany | WGK 3 | | Storage Class | 11 - Combustible Solids |
| | Josiphos SL-J009-1 Pd G3 Usage And Synthesis |
| Reaction | Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.
| | Uses | Josiphos SL-J009-1 Pd G3 is a good catalyst, widely used in various cross-coupling reactions, including: Buchwald-Hartwig cross-coupling reaction, Hiyama Coupling, Negishi Coupling, Heck Reaction, Sonogashira Coupling and Suzuki-Miyaura Coupling, etc. | | General Description | Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst |
| | Josiphos SL-J009-1 Pd G3 Preparation Products And Raw materials |
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