(2R,2'R,3R,3'R) MeO-BIBOP

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(2R,2'R,3R,3'R) MeO-BIBOP Basic information
Product Name:(2R,2'R,3R,3'R) MeO-BIBOP
Synonyms:(2R,2'R,3R,3'R) MeO-BIBOP;(2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole;(2R,2'R,3R,3'R)-3,3'-Bis(tert-butyl)-2,2',3,3'-tetrahydro-4,4'-dimethoxy-2,2'-bi-1,3-benzoxaphosphole;(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-MeO-BIBOP;ZJ-0048;99% ee) (2R,2'R,3R,3'R)-MeO-BIBOP;(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>;2,2'-Bi-1,3-benzoxaphosphole, 3,3'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-4,4'-dimethoxy-, (2R,2'R,3R,3'R)-
CAS:1228758-57-3
MF:C24H32O4P2
MW:446.46
EINECS:
Product Categories:
Mol File:1228758-57-3.mol
(2R,2'R,3R,3'R) MeO-BIBOP Structure
(2R,2'R,3R,3'R) MeO-BIBOP Chemical Properties
Boiling point 562.3±50.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder
AppearanceWhite to off-white Solid
InChIInChI=1S/C24H32O4P2/c1-23(2,3)29-19-15(25-7)11-9-13-17(19)27-21(29)22-28-18-14-10-12-16(26-8)20(18)30(22)24(4,5)6/h9-14,21-22H,1-8H3/t21-,22-,29-,30-/m1/s1
InChIKeyKVPCVNGTJXEQKH-IKTNGCAPSA-N
SMILESO1C2=CC=CC(OC)=C2[P@@](C(C)(C)C)[C@@H]1[C@H]1[P@](C(C)(C)C)C2=C(OC)C=CC=C2O1
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
MSDS Information
(2R,2'R,3R,3'R) MeO-BIBOP Usage And Synthesis
Uses(2R,2′R,3R,3′R)-MeO-BIBOP is a P-chiral biphosphorus ligand used in a variety of asymmetric transition metal-catalyzed transformations including hydrogenations, propargylations, reductions, and hydroformylations.
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)
reaction suitabilityreagent type: ligand
(2R,2'R,3R,3'R) MeO-BIBOP Preparation Products And Raw materials
Tag:(2R,2'R,3R,3'R) MeO-BIBOP(1228758-57-3) Related Product Information
tert-butyl-4-(2,6-dimethoxyphenyl)-2,3-dihydro-1,3-benzoxaphosphol-2-yl]-4-(2,6-dimethoxyphenyl)- (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,5-diphenylcyclopenta-2,4-dien-1-yl)-2,3-dihydrobenzo[d][1,3]oxaphosphole (2S,2'S,3S,3'S)-Ph-BIBOP (R)-3-(tert-butyl)-4-(2,3,5,6-tetrahydrobenzo[1,2-b:5,4-b']difuran-8-yl)-2,3-dihydrobenzo[d][1,3]oxaphosphole (2S,2'S,3S,3'S)-MeO-BIBOP (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (R)-1-(3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-4-yl)-2,5-diphenyl-1H-pyrrole (2S,2'S,3S,3'S)-BIBOP