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Trioctylphosphine

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CAS:4731-53-7
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Trioctylphosphine Basic information
Product Name:Trioctylphosphine
Synonyms:CYTOP(R) 380;TRIOCTYLPHOSPHINE;TRI-N-OCTYLPHOSPHINE;nsc102529;tl411;trioctyl-phosphin;TRIOCTYLPHOSPHINE (CYTOP 380) CYTEC QUALITY;TRIOCTYLPHOSPHINE, TECH., 90%
CAS:4731-53-7
MF:C24H51P
MW:370.64
EINECS:225-234-2
Product Categories:Achiral Phosphine;Alkyl Phosphine;organophosphorus ligand;Phosphine Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Tertiary Phosphines;Mitsunobu Reaction;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Synthetic Organic Chemistry;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:4731-53-7.mol
Trioctylphosphine Structure
Trioctylphosphine Chemical Properties
Melting point 30°C
Boiling point 284-291 °C50 mm Hg(lit.)
density 0.831 g/mL at 25 °C(lit.)
refractive index n20/D 1.468(lit.)
Fp 297 °F
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder or Crystalline Powder
color White to off-white
Specific Gravity0.831
Water Solubility Immiscible with water.
Sensitive Air Sensitive
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
BRN 1776995
InChIInChI=1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChIKeyRMZAYIKUYWXQPB-UHFFFAOYSA-N
SMILESP(CCCCCCCC)(CCCCCCCC)CCCCCCCC
CAS DataBase Reference4731-53-7(CAS DataBase Reference)
EPA Substance Registry SystemPhosphine, trioctyl- (4731-53-7)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-36/37/38
Safety Statements 26-36/37/39-45-37/39
RIDADR UN 1760 8/PG 2
WGK Germany 2
RTECS SZ3450000
10-13-23
TSCA TSCA listed
HazardClass 8
PackingGroup II
HS Code 29310099
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsEye Dam. 1
Skin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Trioctylphosphine Usage And Synthesis
DescriptionTrioctylphosphine (also known as Tri-n-octylphosphine, abbreviated as TOP) is a weakly basic organophosphorus compound that can be used in the synthesis of nanomaterials (such as metallic nanoparticles). It also serves as the most popular organophosphorus source in oil-phase synthesis, a stabiliser for certain nanorods, and acts as a solvent in certain chemical processes.
Chemical PropertiesTrioctylphosphine abbreviated as TOP, is a colorless liquid with garlic odor, easily oxidized to tri-n-octylphosphine oxide in air.
UsesTri-n-octylphosphine is used for coating zinc sulfide shells on cadmium-selenium quantum dot core by successive ionic layer adsorption and reaction method. It acts as a precursor to trioctylphosphine oxide. Further, it is used as a solvent for cadmium and selenium precursors. It also serves as a common reagent in the chemical synthesis of nanoparticles. It acts as a precursor to trioctylphosphine oxide.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Trioctylphosphine Preparation Products And Raw materials
Raw materialsdioctylmagnesium-->Trioctylphosphine oxide
Preparation Productstrioctylphosphine sulphide
Tag:Trioctylphosphine(4731-53-7) Related Product Information
Tributyltin Hydride N,N-Dipropyl-1-propanamine Tributylphosphine BISMUTH TELLURIDE TRI-N-OCTYLPHOSPHINE OXIDE,Tri-n-octylphosphine oxide: (Trioctylphophine oxide),Tri-n-octylphosphine oxide, 99% 25g Copper(II) chloride PHOSPHOROUS ACID TRI-O-CRESYL ESTER MOLYBDENUM(V) CHLORIDE Tri-tert-butylphosphine Fluorotributyltin Trioctylphosphine TETRA-N-OCTYLPHOSPHONIUM BROMIDE ETHYLTRI-N-OCTYLPHOSPHONIUM BROMIDE Phosphine TETRAOCTYLPHOSPHONIUM HYDROXIDE SOL., ~20% IN METHANOL AURORA KA-1151 TRIS(1H,1H,2H,2H-PERFLUOROOCTYL)PHOSPINE

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