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| | (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Basic information | | Reaction |
| Product Name: | (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) | | Synonyms: | (1R,2R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYDENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II);(1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)COBALT(II);(1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II);CyclohexanediaminoNNbisditbutylsalicylidene;(R,R)-(-)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL ID -ENE)-1,2-CYCLOHEXANEDIAMINOCOBALT(II;(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)cobalt(II);(1r,2r)-(-)-1,2-cyclohexanediamino-n,n'-bis(3,5- di-t-butylsalicylidene)cobalt;(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) | | CAS: | 176763-62-5 | | MF: | C36H52CoN2O2 | | MW: | 603.74 | | EINECS: | | | Product Categories: | Jacobsen Metal;Co;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis;Kinetic ResolutionChiral Catalysts, Ligands, and Reagents;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs | | Mol File: | 176763-62-5.mol |  |
| | (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Chemical Properties |
| Melting point | >350 °C(lit.) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | Powder | | color | Orange to red to brown | | InChIKey | ZFWPDJKMASHRPT-DKZUAMKGNA-L | | SMILES | C12O[Co]OC3=C(C=N[C@@H]4CCCC[C@H]4N=CC=1C=C(C(C)(C)C)C=C2C(C)(C)C)C=C(C(C)(C)C)C=C3C(C)(C)C |t:6,15,&1:8,13,r| |
| | (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Usage And Synthesis |
| Reaction |
- Catalyst used in the kinetic resolution of racemic, terminal epoxides yielding a chiral diol and the unreacted enantiomer of the epoxide.
- Precursor to a Co(III) catalyst for the kinetic resolution of terminal epoxides with alcohols.
- Desymmetrization of meso-epoxides with carboxylic acids and fluoride.
- Catalyst for asymmetric cyclopropanation of styrene.
- Catalyst for copolymerization of CO2 and epoxides.
- Enantioselective intramolecular openings of oxetanes.
| | Chemical Properties | Orange to red-brown powder | | Uses | Catalyst for the hydrolytic kinetic resolution of terminal epoxides and the enantioselective ring opening of meso epoxides. |
| | (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) Preparation Products And Raw materials |
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