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Product Name:THALLIC ACETATE
CAS:2570-63-0
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| | THALLIC ACETATE Basic information |
| | THALLIC ACETATE Chemical Properties |
| Melting point | 182 °C (dec.)(lit.) | | storage temp. | Poison room | | solubility | sol hot acetic acid, alcohols, H2O. | | form | Crystalline Powder | | color | White to off-white | | BRN | 3693590 | | InChI | 1S/3C2H4O2.Tl/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 | | InChIKey | SMRRYUGQTFYZGD-UHFFFAOYSA-K | | SMILES | [TlH].CC(O)=O | | CAS DataBase Reference | 2570-63-0(CAS DataBase Reference) | | EPA Substance Registry System | Acetic acid, thallium(3+) salt (2570-63-0) |
| Hazard Codes | T+,N | | Risk Statements | 26/28-33-51/53-26/27/28 | | Safety Statements | 13-28-45-61-36/37/39-22 | | RIDADR | UN 1707 6.1/PG 2 | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | 6.1 | | PackingGroup | II | | HS Code | 29152900 | | Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | | Hazard Classifications | Acute Tox. 2 Inhalation
Acute Tox. 2 Oral
Aquatic Chronic 2
STOT RE 2 |
| | THALLIC ACETATE Usage And Synthesis |
| Chemical Properties | white to off-white crystalline powder | | Uses | Thallium(III) Acetate is used for oxidation of alkenes and alkynes; oxidation of conjugated dienes; hydroxylation of double bonds; cleavage of cyclopropane rings; oxidation of enamines; oxidative rearrangements; bromination of aromatic compounds; oxidation of thiols and p-toluenesulfonylhydrazones; formation of acyloxy carboxylic acids; oxidative cyclizations. | | Preparation | Thallium(III) Acetate can also be prepared by dissolving
thallium(III) oxide in acetic acid and acetic anhydride and stirring at 80-90 °C. The solution is filtered, cooled and the product
obtained is recrystallized. | | reaction suitability | core: thallium
reagent type: catalyst | | storage | Thallium(III) Acetate remains stable for long periods if kept in a well-sealed desiccator and away from light. It
is extremely poisonous. Use in a fume hood. |
| | THALLIC ACETATE Preparation Products And Raw materials |
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