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1-Methyl-L-histidine

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Products Intro: Product Name:H-His(1-Me)-OH
CAS:332-80-9
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Products Intro: Product Name:1-methyl-l-histidine
CAS:332-80-9
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CAS:332-80-9
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Products Intro: Product Name:1-Methyl-L-histidine
CAS:332-80-9
Purity:99.83% Package:5mg;40USD|10mg;55USD|25mg;88USD Remarks:REAGENT;FOR LABORATORY USE ONLY
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Products Intro: Product Name:NT-Methyl-His-OH
CAS:332-80-9

1-Methyl-L-histidine manufacturers
1-Methyl-L-histidine Basic information
Product Name:1-Methyl-L-histidine
Synonyms:METHYLHISTIDINE, L-1-;METHYLHISTIDINE, L-3-;1-METHYL-L-HISTIDINE;3-(1-METHYLIMIDAZOL-4-YL)-L-ALANINE;3-(1-METHYLIMIDAZOL-5-YL)-L-ALANINE;1-Methyl-L-histidine >=98.0% (TLC);1-N-Methyl-L-histidine;N1-Methyl-L-histidine
CAS:332-80-9
MF:C7H11N3O2
MW:169.18
EINECS:206-368-0
Product Categories:Pharmaceutical Raw Materials;Histidine [His, H];Amino Acids and Derivatives;Amino acids methyl、ethyl、t-butyl series;Amino Acids & Derivatives;Heterocycles;Inhibitors
Mol File:332-80-9.mol
1-Methyl-L-histidine Structure
1-Methyl-L-histidine Chemical Properties
Melting point ~240 °C (dec.) (lit.)
alpha -24 º (c=2% in H2O)
Boiling point 298.47°C (rough estimate)
density 1.2509 (rough estimate)
refractive index 1.5950 (estimate)
storage temp. 2-8°C(protect from light)
solubility Methanol (Slightly), Water (Slightly, Sonicated)
pka1.69(at 25℃)
form Solid
color Off-White to Pale Beige
Optical Rotation[α]20/D 24±1°, c = 2% in H2O
BRN 9727
Stability:Hygroscopic
Major Applicationpeptide synthesis
InChI1S/C7H11N3O2/c1-10-3-5(9-4-10)2-6(8)7(11)12/h3-4,6H,2,8H2,1H3,(H,11,12)/t6-/m0/s1
InChIKeyBRMWTNUJHUMWMS-LURJTMIESA-N
SMILESCn1cnc(C[C@H](N)C(O)=O)c1
CAS DataBase Reference332-80-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25-22
WGK Germany 3
HS Code 29332900
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
1-Methyl-L-histidine Usage And Synthesis
Chemical PropertiesBeige powder
UsesThe urinary 1- and 3-methylhistidine (1- and 3-MH) metabolites as potential biomarkers of skeletal muscle toxicity. These metabolites were highly correlated to sex-, dose-, and time-dependent development of cerivastatin-induced myotoxicity. Natural but non-proteinogenic amino acid; employed as index of muscle protein breakdown.
DefinitionChEBI: N(tele)-methyl-L-histidine is a L-histidine derivative in which the methyl group is at N(tele)-position. It has a role as a human metabolite. It is a L-histidine derivative and a non-proteinogenic L-alpha-amino acid. It is a tautomer of a N(tele)-methyl-L-histidine zwitterion.
reaction suitabilityreaction type: solution phase peptide synthesis
1-Methyl-L-histidine Preparation Products And Raw materials
Tag:1-Methyl-L-histidine(332-80-9) Related Product Information
Methylparaben Kresoxim-methyl Bensulfuron methyl Methyl acrylate L-Histidine 1,3-Dimethylbarbituric acid L-Alanine Carboxymethyl cellulose Sodium carboxymethyl cellulose 3-METHYL-L-HISTIDINE Thiophanate-methyl N,N-Dimethylformamide Methyl N-Boc-N'-benzyloxymethyl-L-histidine N-Fmoc-N'-Trityl-L-histidine pentafluorophenyl ester N,N'-Bis(9-fluorenylmethyloxycarbonyl)-L-histidine Z-HIS(BZL)-OH Methyl bromide