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Tri-n-butylphosphonium tetrafluoroborate

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Tri-n-butylphosphonium tetrafluoroborate manufacturers

Tri-n-butylphosphonium tetrafluoroborate Basic information
Reaction
Product Name:Tri-n-butylphosphonium tetrafluoroborate
Synonyms:TRI-N-BUTYLPHOSPHINE TETRAFLUOROBORATE,&;Tri-n-butylphosphoniumtetrafluoroborate,99%;tributylphosphine tetrafluoroborate;Tributylphosphonium tetrafluoroborate;Tributylphosphine tetrafluoroborate 97%;[n-Bu3PH]BF4;Tributylphosphine tetrafluoroborate,97%;tributylphosphanium,tetrafluoroborate
CAS:113978-91-9
MF:C12H28BF4P
MW:290.13
EINECS:
Product Categories:Achiral Phosphine;Alkyl Phosphine;P-BF4;organophosphine salt;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:113978-91-9.mol
Tri-n-butylphosphonium tetrafluoroborate Structure
Tri-n-butylphosphonium tetrafluoroborate Chemical Properties
Melting point 50-53 °C (lit.)
Fp >221 °F
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
InChIInChI=1S/C12H27P.BF4/c1-4-7-10-13(11-8-5-2)12-9-6-3;2-1(3,4)5/h4-12H2,1-3H3;/q;-1/p+1
InChIKeyNCHAZLRRIGGCER-UHFFFAOYSA-O
SMILES[B-](F)(F)(F)F.[PH+](CCCC)(CCCC)CCCC
Safety Information
Risk Statements 36/37/38
Safety Statements 22-24/25
WGK Germany 3
HS Code 2931599090
Storage Class13 - Non Combustible Solids
MSDS Information
ProviderLanguage
SigmaAldrich English
Tri-n-butylphosphonium tetrafluoroborate Usage And Synthesis
Reaction
  1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
  2. Catalyst in Baylis-Hillman reactions.
  3. Azide reductions.
  4. Acylation of alcohols by anhydrides.
  5. Ligand for formate reduction of allyl carbonates.
  6. Synthesis of aromatic nitriles via Pd C-H functionalization. 
Reactions of 113978-91-9_1
Reactions of 113978-91-9_2
General DescriptionMay contain approximately 5% of other butyl isomers.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Tri-n-butylphosphonium tetrafluoroborate Preparation Products And Raw materials
Raw materialsDichloromethane-->Magnesium sulfate-->Fluoroboric acid-->Tributylphosphine
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