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| | Dimethyl chloromalonate Basic information |
| | Dimethyl chloromalonate Chemical Properties |
| Boiling point | 105-106 °C/19 mmHg (lit.) | | density | 1.305 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.437(lit.) | | Fp | 224 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | pka | 9.02±0.46(Predicted) | | form | clear liquid | | color | Colorless to Light yellow | | BRN | 1768415 | | InChI | InChI=1S/C5H7ClO4/c1-9-4(7)3(6)5(8)10-2/h3H,1-2H3 | | InChIKey | LNBQBURECUEBKZ-UHFFFAOYSA-N | | SMILES | C(OC)(=O)C(Cl)C(OC)=O | | CAS DataBase Reference | 28868-76-0(CAS DataBase Reference) |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3265 8/PG 2 | | WGK Germany | 3 | | F | 21 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 2917198090 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Skin Corr. 1B |
| | Dimethyl chloromalonate Usage And Synthesis |
| Uses | Dimethyl chloromalonate is suitable for use in the synthesis of 4,5,6-trichloropyrimidine. It may be used in the stereoselective synthesis of highly functionalized nitrocyclopropanes. It may be used in one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes. | | General Description | Dimethyl chloromalonate (dimethyl 2-chloromalonate) is a dialkyl 2-substituted malonate. Carbanions of dimethyl chloromalonate are reported to react with naphthoquinone derivatives, via vicarious nucleophilic substitution or oxidative nucleophilic substitution of hydrogen processes. Dimethyl chloromalonate is reported to react with hydroquinone and monosubstituted hydroquinones to afford 2-oxido-benzo[b]furan derivatives. Synthesis of dimethyl 2-chloromalonate, via chlorination of dimethyl malonate has been reported. |
| | Dimethyl chloromalonate Preparation Products And Raw materials |
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