(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers list
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Products Intro: Product Name:(1R,2R)-(+)-1,2-Diaminocyclohexane- N,N'-bis(2'-diphenylphosphinobenzoyl), (R,R)-DACH-Phenyl Trost Ligand
CAS:138517-61-0
Purity:98% Package:10MG;50MG;100MG,1G,5G,10G
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Products Intro: Product Name:(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS:138517-61-0
Purity:98% Package:1KG;1USD
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Products Intro: Product Name:(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N’-BIS(2’-DIPHENYLPHOSPHINOBENZOYL)
CAS:138517-61-0
Purity:0.98 Package:1KG;10KG;50KG
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Products Intro: Product Name:(1r,2r)-(+)-n,n'-bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane
CAS:138517-61-0
Purity:0.99 Package:1kg
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Products Intro: Product Name:(R,R)-DACH-phenyl Trost ligand
CAS:138517-61-0
Purity:99% HPLC Package:5KG;1KG

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information
Reaction
Product Name:(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl;Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide];TROST LIGAND;(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1R,2R)-(+)-1,2-TROST LIGAND;"N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand"
CAS:138517-61-0
MF:C44H40N2O2P2
MW:690.75
EINECS:
Product Categories:Chiral Nitrogen;DACH&Trost Series
Mol File:138517-61-0.mol
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Structure
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties
Melting point 134-136°C
alpha +130° (c 1.0, methanol)
Boiling point 817.0±65.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
pka13.35±0.40(Predicted)
color white to off-white
Optical Rotation[α]20/D +131°, c = 1 in methanol
InChIKeyAXMSEDAJMGFTLR-UHFFFAOYSA-N
SMILESC1(NC(=O)C2=CC=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)CCCCC1NC(=O)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
Safety Information
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis
ReactionThe palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. Reactions of 138517-61-0_1
Reactions of 138517-61-0_2
Reactions of 138517-61-0_3
UsesTrost Ligands for Asymmetric Allylic Alkylation
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials
Tag:(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)(138517-61-0) Related Product Information
(1R,2R)-(+)-N,N'-DI-P-TOSYL-1,2-CYCLOHEXANEDIAMINE (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-Diphenylphosphinobenzaldehyde Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine N-(2-AMINO-CYCLOHEXYL)-ACETAMIDE TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE (1R,2R)-(-)-1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine

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