| Company Name: |
J & K SCIENTIFIC LTD.
|
| Tel: |
18210857532; 18210857532 |
| Email: |
jkinfo@jkchemical.com |
| Products Intro: |
Product Name:(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP CAS:828927-94-2 Purity:min. 95% Package:1g;250mg
|
| Company Name: |
Bide Pharmatech Ltd.
|
| Tel: |
400-164-7117 13681763483 |
| Email: |
product02@bidepharm.com |
| Products Intro: |
Product Name:(S)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine CAS:828927-94-2 Purity:97% Package:50mg;100mg;250mg;1g Remarks:BD635821
|
| Company Name: |
LaaJoo
|
| Tel: |
021-60702684 18516024827 |
| Email: |
huang.jiayi@sinocompound.com |
| Products Intro: |
Product Name:(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine CAS:828927-94-2 Purity:97% Package:100mg
|
| Company Name: |
Rhawn Reagent
|
| Tel: |
400-400-1332688 18019345275 |
| Email: |
amy@rhawn.cn |
| Products Intro: |
Product Name:(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE CAS:828927-94-2
|
(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE manufacturers
|
| | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Basic information | | Reaction |
| Product Name: | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE | | Synonyms: | (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;(R,S)-O-PINAP;(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine, min. 97% (R,S)-O-PINAP;(S)-(-)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethoxy]phthalazine,Min.95%(R,S)-O-PINAP;Phthalazine, 1-[2-(diphenylphosphino)-1-naphthalenyl]-4-[(1R)-1-phenylethoxy]-, (1S)-;CID 15604713 | | CAS: | 828927-94-2 | | MF: | C38H29N2OP | | MW: | 560.62 | | EINECS: | | | Product Categories: | Chiral Phosphine;PINAP Series | | Mol File: | 828927-94-2.mol | ![(S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Structure](CAS/GIF/828927-94-2.gif) |
| | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Chemical Properties |
| Melting point | 178-181°C | | alpha | -160.4° (c 0.53, CHCl3) | | Boiling point | 726.4±60.0 °C(Predicted) | | storage temp. | 2-8°C, protect from light, stored under nitrogen | | form | crystal | | pka | 3.45±0.30(Predicted) | | color | colorless | | Sensitive | air sensitive |
| | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Usage And Synthesis |
| Reaction |
- The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
- With rhodium, enantioselective hydroboration of alkenes as a route to chiral alcohols.
- With silver, catalytic, enantioselective, azomethine cycloaddition with acrylates.
|
| | (S)-(-)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHOXY]PHTHALAZINE Preparation Products And Raw materials |
|