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Potassium tetrathionate

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Potassium tetrathionate Basic information
Product Name:Potassium tetrathionate
Synonyms:Tetrathionicacid,dipotassiumsalt;POTASSIUM TETRATHION;dipotassiumtetrathionate;Tetrathionic acid, potassium salt (1:2);Potassium Tetrethionate;Potassium tetrathionate 99%min;Tetrathionsaeure;Potassium tetrathionate
CAS:13932-13-3
MF:K2O6S4
MW:302.45
EINECS:237-702-3
Product Categories:Metal and Ceramic Science;Potassium Salts;Salts
Mol File:13932-13-3.mol
Potassium tetrathionate Structure
Potassium tetrathionate Chemical Properties
density 2.96 g/mL at 25 °C (lit.)
bulk density770kg/m3
storage temp. 2-8°C
solubility 232g/l
form solid
AppearanceOff-white to yellow Solid
Water Solubility 232g/L
Cosmetics Ingredients FunctionsREDUCING
InChIInChI=1S/2K.H2O6S4/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2
InChIKeyUVTKHPSJNFFIDG-UHFFFAOYSA-L
SMILESS([O-])(=O)(=O)SSS([O-])(=O)=O.[K+].[K+]
EPA Substance Registry SystemPotassium tetrathionate (13932-13-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
RTECS XF6450000
TSCA TSCA listed
HS Code 2842 90 80
Storage Class11 - Combustible Solids
ToxicityLD50 orally in Rabbit: > 2000 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
Potassium tetrathionate Usage And Synthesis
UsesUsed in the preparation of tetrathionate hydrolase assay from Acidithiobacillus caldus, it acts as an energy source.
DefinitionChEBI: A potassium salt composed of potassium and tetrathionate ions in a 2:1 ratio.
PreparationPotassium tetrathionate is prepared by a similar reaction—the reaction of S2Cl2 with sulphurous acid, followed by KOH neutralization, as shown by the equations.
2H2S03 + S2C12->H2S406+2HCl
H2S406+2KOH -> K2S406 + 2H2O or by the reaction of iodine with K2S2O3.
2K2S203 + I2 -> K2S406+2KI.
The reaction is carried out in an ethanol-water mixture, a medium in which the potassium tetrathionate is insoluble; the K2S406 precipitates as colorless shiny platelets.
General DescriptionThe crystal structure of potassium tetrathionate is monoclinic with a=22.081o, b=7.991o, c=10.108o
Potassium tetrathionate Preparation Products And Raw materials
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