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Cesium iodide

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Cesium iodide Basic information
Description References
Product Name:Cesium iodide
Synonyms:Cesium iodide, 99.9%, for analysis;Cesium iodide, for analysis;Cesium Iodide (Metals Basis);Cesium iodide/ 99.99%;CESIUM IODIDE, 99.7%;tricesiumtriiodide;CESIUM IODIDE;CESIUM IODINE
CAS:7789-17-5
MF:CsI
MW:259.81
EINECS:232-145-2
Product Categories:Cesium;Cesium Salts;Crystal Grade Inorganics;Cs;Materials Science;Metal and Ceramic Science;Ultra-High Purity Materials;Crystal Grade Inorganics;Metal and Ceramic Science;Salts;Alphabetic;C;CA - CGAnalytical Standards;MS MarkersPhysical Properties;MS Standards;Single Compounds;Spectroscopy;Electronic Materials;Materials Science;Micro/Nanoelectronics;Cesium Salts;CesiumMetal and Ceramic Science;metal halide;bc0001
Mol File:7789-17-5.mol
Cesium iodide Structure
Cesium iodide Chemical Properties
Melting point 626 °C (lit.)
Boiling point 1280 °C
density 4.51 g/mL at 25 °C (lit.)
refractive index 1.7876
Fp 1280°C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility soluble in ethanol, methanol, acetone
form beads
Specific Gravity4.51
color White
PHpH(50g/l, 25℃) : 5.0~9.0
Water Solubility 74 g/100 mL (20 ºC)
Sensitive Hygroscopic
Merck 14,2014
Exposure limitsACGIH: TWA 0.01 ppm
Dielectric constant5.6(Ambient)
Stability:Stable. Deliquescent.
Major Applicationcleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
InChI1S/Cs.HI/h;1H/q+1;/p-1
InChIKeyXQPRBTXUXXVTKB-UHFFFAOYSA-M
SMILES[I-].[Cs+]
CAS DataBase Reference7789-17-5(CAS DataBase Reference)
NIST Chemistry ReferenceCesium iodide(7789-17-5)
EPA Substance Registry SystemCesium iodide (CsI) (7789-17-5)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38-42/43-43
Safety Statements 22-36/37-45
RIDADR UN 3077 9 / PGIII
WGK Germany 2
RTECS FL0350000
8
TSCA TSCA listed
HazardClass 9
HS Code 28276000
Storage Class13 - Non Combustible Solids
Hazard ClassificationsAquatic Acute 1
Repr. 2
ToxicityLD50 i.p. in rats: 1.4 g/kg (Cochran)
MSDS Information
ProviderLanguage
Cesium iodide English
ACROS English
SigmaAldrich English
ALFA English
Cesium iodide Usage And Synthesis
DescriptionCesium iodide is a soft material and extremely hygroscopic. Cesium iodide scintillators have been used extensively for indirect x-ray imaging detectors, such as for CT examinations. Cesium iodide is also used to construct electromagnetic shower detector for the CLEO II experiment, which investigates electron-positron annihilation at center-of-mass energies near 10 GeV. Cesium iodide is useful for beam splitters for Far IR spectrophotometers and IR transmission windows.
References [1] W. Zhao, G. Ristic, J. A. Rowlands, X-ray imaging performance of structured cesium iodide scintillators, Medical Physics, 2004, vol. 31, 2594-605
[2] E. Blucher, B. Gittelmann, B. K. Heltsley, J. Kandaswamy, R. Kowalewski, Y.Kubota, N. Mistry and S. Stone, Tests of cesium iodide crystals for an electromagnetic calorimeter, Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 1986, vol. 249, 201-227
[3] M. Völk, O. W. Hamer, S. Feuerbach, M. Strotzer, Dose reduction in skeletal and chest radiography using a large-area flat-panel detector based on amorphous silicon and thallium-doped cesium iodide: technical background, basic image quality parameters, and review of the literature, European Radiology, 2004, vol. 14, 827-834
[4] M. V. Mastryukov. “Preparation of Extrapure Cesium Iodide.” Inorganic Materials 56 10 (2020): 1050–1054.
Chemical Propertieswhite crystalline powder
UsesPrisms for infrared spectroscopy; in x-ray fluorescent screens, scintillation counters.
UsesCesium iodide (CsI) is a kind of ionic compound that has been widely used as scintillators in many areas such as X-ray image intensifier tubes, photocathodes, and display devices.
Cesium iodide is used in scintillation counters(Geiger counters) to measure levels of external radiation. It is also useful as a "getter" to remove air molecules remaining in vacuum tubes.
Cesium Iodide is a material with high γ-ray stopping power due to its relative high density and atomic number. For scintillation counting, it is used either in its un-doped form or doped with sodium or thallium.
CsI is resistant to thermal and mechanical shock. The physical characteristics of CsI are independent of the activator used. Compared to NaI(Tl), it is relatively soft and plastic, and does not cleave. Because it has no cleavage plane, it is quite rugged-which makes it well-suited for well logging, space research or other applications where severe shock conditions are encountered.
UsesCesium iodide is used in FT-IR (Fourier Transform Infrared Spectrometers) as a beamsplitter. Cesium Iodide exhibits high gamma-ray stopping power. Useful as input phosphor in fluoroscopy equipment, and efficient photocathode for extreme ultraviolet wavelengths. Fast and dense scintillating material - useful in electromagnetic calorimetry in particle physics.
Production MethodsA single crystal can be grown from a melt solution by both the Kyropoulus method and the Stockbarger method.
General DescriptionCesium iodide is a simple ionic salt. It has the capacity to undergo second order transformation from cubic B2 structure to body-centered tetragonal structure at low pressures. It is mostly used as input screens of X-ray image intensifiers.
Flammability and ExplosibilityNon flammable
Safety ProfileModerately toxic by ingestion and intraperitoneal routes. See also CESIUM and IODIDES. When heated to decomposition, it emits toxic fumes of I-.
SynthesisThe main method for preparing cesium iodide-based single crystals is Kyropoulos growth, which allows one to obtain cylindrical ingots weighing up to several tens of kilograms.
Cs2CO3+ 2HI→2CsI+H2O+CO2↑
Technically, pure CsI was prepared by dissolving cesium carbonate in hydriodic acid at room temperature in a vessel from niobium, which was nonreactive with cesium iodide at elevated temperatures. The solution was heated to boiling at pH 3 to completely dissolve the caesium carbonate because the niobium vessel was unstable in an acid medium.The hot solution was filtered and boiled down at a temperature near 393 K. After crystallization, the material was vacuum-dried in a quartz ampule[4].
Solubility in waterCesium iodide is soluble in water, with a solubility of 44/100 g H2O (0℃ and 160/100 g H2O (61℃). It is soluble in alcohol. One should handle it carefully, because it is deliquescent.
Purification MethodsCrystallise it from warm water (1mL/g) by cooling to -5o.
Structure and conformationThe space lattice of CsI belongs to the cubic system, and its cesium chloride structure has a lattice constant of a=0.8529 nm.
Cesium iodide Preparation Products And Raw materials
Tag:Cesium iodide(7789-17-5) Related Product Information
Iodine Potassium iodide Propidium iodide Lead(II) iodide Cesium chloride Caesium fluoride Cesium bromide CESIUM DODECAHYDRODODECABORATE Cesium carbonate CESIUM HYDROXIDE, HYDRATE (99.9%-CS) Cesium sulfate SAMARIUM(II) IODIDE BISMUTH POTASSIUM IODIDE Sodium iodide Iodobenzene Cuprous iodide Nessler's Reagent Zinc iodide Caesium Iodide

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