(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE

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Products Intro:	Product Name:(\|R\|)-()-\|N\|,\|N\|-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine CAS:55700-44-2 Purity:99% Package:100KG;2USD\|25KG;4USD\|1KG;5USD

Company Name:	career henan chemical co
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Products Intro:	Product Name:(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE CAS:55700-44-2 Purity:99% Package:1KG;1USD

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Products Intro:	Product Name:(R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine CAS:55700-44-2 Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;706T/drum;

Company Name:	SHANGHAI T&W PHARMACEUTICAL CO., LTD.
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Products Intro:	Product Name:(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine CAS:55700-44-2 Purity:99% HPLC Package:5KG;1KG

Company Name:	Zhengzhou Alfa Chemical Co.,Ltd
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Products Intro:	Product Name:(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE CAS:55700-44-2 Purity:95%min Package:5g;25g;100g;500g;1kg;25kg

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE manufacturers

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Basic information

Product Name:	(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
Synonyms:	(-)-(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE;(R) -NN-dimethyl-1-((S) -2-diphenylphosphorus) ferrocene) ethylamine;(R)-(-)-N,N-DIMETHYL-1-(2-DIPHENYLPHOSPHINO)FERROCENYLETHYLAMINE;(R)-(S)-PPFA;(-)-(R)-N,N-dimethyl-1-((S)-2-(diphenyl-phosphino;(R)-N,N-Dimethyl-1-((S)-2-(diphenylphosphino)ferro;Josiphos SL-0000-2
CAS:	55700-44-2
MF:	C26H28FeNP10*
MW:	441.33
EINECS:	633-502-9
Product Categories:	Chiral Phosphine;Asymmetric Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Other Chiral Ligands
Mol File:	55700-44-2.mol

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Chemical Properties

Melting point	141-143 °C(lit.)
alpha	-355 º (C=0.6 IN ETOH)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
form	solid
color	Light yellow to Yellow to Orange
Optical Rotation	[α]20/D 355°, c = 0.6 in ethanol
Water Solubility	Insoluble in water.
Sensitive	Air Sensitive
InChI	1S/C21H23NP.C5H5.Fe/c1-17(22(2)3)20-15-10-16-21(20)23(18-11-6-4-7-12-18)19-13-8-5-9-14-19;1-2-4-5-3-1;/h4-17H,1-3H3;1-5H;/t17-;;/m1../s1
InChIKey	RCAFPSZHKFOLEE-ZEECNFPPSA-N
SMILES	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)C

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-36-36/37/38
RIDADR	3288
WGK Germany	3
HazardClass	6.1
PackingGroup	III
HS Code	29319090
Storage Class	11 - Combustible Solids
Hazard Classifications	Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Usage And Synthesis

Chemical Properties	Yellow solid
Uses	Ligand used in the enantioselective vinylation of aldehydes.
Application	(R)-N,N-dimethyl-1-[(s)-2-(diphenylphosphino)ferrocenyl]ethylamine is an effective chiral phosphine ligand for nickel- or palladium-catalyzed asymmetric cross-couplings of organomagnesium or zinc reagents with alkenyl bromides and for palladium-catalyzed asymmetric hydrosilylations of 1,3-dienes.
reaction suitability	reaction type: Asymmetric synthesis reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Cross Couplings
storage	stable in air for years, but best kept sealed in a refrigerator.

(R)-N,N-DIMETHYL-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE Preparation Products And Raw materials

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