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| | meso-Tetra(4-carboxyphenyl)porphine Basic information |
| Product Name: | meso-Tetra(4-carboxyphenyl)porphine | | Synonyms: | TETRACARBOXYPHENYLPORPHYRIN;TETRAKIS(4-CARBOXYPHENYL)PORPHINE;RARECHEM AS SA 0048;NICKEL IONOPHORE II;MESO-TETRA(4-CARBOXYPHENYL)PORPHINE;MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID;5,10,15,20-TETRA(4-CARBOXYPHENYL)PORPHYRIN;5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN | | CAS: | 14609-54-2 | | MF: | C48H30N4O8 | | MW: | 790.77 | | EINECS: | | | Product Categories: | porphine (porphyrin) ligand;Porphyrins;Synthetic Porphyrins;Analytical Chemistry;Biochemistry;Chelating Reagents;Ligands for Pharmaceutical Research;Magnetic Resonance Imaging (Chelating Reagents);Porphines | | Mol File: | 14609-54-2.mol |  |
| | meso-Tetra(4-carboxyphenyl)porphine Chemical Properties |
| Melting point | >300 °C | | density | 1.462±0.06 g/cm3(Predicted) | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | form | Powder | | color | purple | | Appearance | Purple to Black Solid | | λmax | 411 nm | | InChIKey | HHDUMDVQUCBCEY-LWQDQPMZSA-N | | SMILES | C1(C2=CC=C(C=C2)C(O)=O)=C2N=C(C(C3=CC=C(C=C3)C(O)=O)=C3NC(=C(C4=CC=C(C=C4)C(O)=O)C4=NC(=C(C5=CC=C(C=C5)C(O)=O)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:24,t:10,27,41| |
| | meso-Tetra(4-carboxyphenyl)porphine Usage And Synthesis |
| Description | 5,10,15,20-(tetra-4-carboxyphenyl)porphyrin is a sensor for Ni2+. | | Uses | 4,4′,4′′, 4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) (H2TCPP) can be used to fabricate three dimensional Ru polymer complex. It can be grafted on SiO2/Nb2O5 substrate and subsequently metallized to investigate catalytic oxidation of hydrazine. | | Uses | meso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes. | | Uses | Nickel ionophore II is a selective sensor for Ni(II) ions. | | General Description | Visit our Sensor Applications portal to learn more. | | Synthesis | 
General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent). |
| | meso-Tetra(4-carboxyphenyl)porphine Preparation Products And Raw materials |
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