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Lithium trifluoromethanesulfonate

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CAS:33454-82-9
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  • Lithium triflate
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  • CAS:33454-82-9
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  • CAS:33454-82-9
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Lithium trifluoromethanesulfonate Basic information
Product Name:Lithium trifluoromethanesulfonate
Synonyms:ithium trifL;Lithiumtrifluoromethanesulphonate97%;LITHIUM TRIFLUOROMETHANESULFONATE, 99.99 5%;Lithium Trifluoro Methylsulphate;Lithium triflate~Trifluoromethanesulphonic acid lithium salt;Lithiumtrifluoromethanesulfonate,99%(Lithiumtriflate);Lithium trifluoromethanesulphonate 97%;Methanesulfonic acid,1,1,1-trifluoro-, lithiuM salt (1:1)
CAS:33454-82-9
MF:CF3LiO3S
MW:156.01
EINECS:251-528-5
Product Categories:metal triflate compounds;Organic-metal salt;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Li (Lithium) Compounds;Metal Triflates;Synthetic Organic Chemistry;Typical Metal Compounds;triflate
Mol File:33454-82-9.mol
Lithium trifluoromethanesulfonate Structure
Lithium trifluoromethanesulfonate Chemical Properties
Melting point >300 °C (lit.)
density 1,9 g/cm3
storage temp. Inert atmosphere,Room Temperature
solubility Water
form Powder
color White or colorless
Water Solubility soluble
Sensitive Moisture Sensitive
BRN 4301818
Stability:hygroscopic
InChIInChI=1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKeyMCVFFRWZNYZUIJ-UHFFFAOYSA-M
SMILESC(F)(F)(F)S([O-])(=O)=O.[Li+]
LogP0.3 at 25℃ and pH1
CAS DataBase Reference33454-82-9(CAS DataBase Reference)
EPA Substance Registry SystemMethanesulfonic acid, trifluoro-, lithium salt (33454-82-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
3-10
Hazard Note Irritant
TSCA TSCA listed
HS Code 29049020
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
ACROS English
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Lithium trifluoromethanesulfonate Usage And Synthesis
Chemical Propertieswhite powder
Properties and Applications Lithium trifluoromethanesulfonate is highly soluble in water and organic solvents and shows excellent ion conductivity. It is highly soluble in polar organic solvents such as dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl acetate, and others. This compound exhibits good thermal stability and has a non-coordinating anion (triflate), which helps prevent unwanted reactions with other components in electrochemical systems.
UsesLithium trifluoromethanesulfonate is mixed with ceramic filler to prepare polyethylene oxide films in order to improve the electrochemical and mechanical characteristics of the membrane, which is used in the lithium batteries. It acts as a doping salt used in the preparation of nano manganese-composite polymer electrolytes.
General DescriptionThis product has been enhanced for energy efficiency.
Synthesis A 316L stainless steel autoclave was charged with 1678 g of a 10.0% aqueous solution of lithium hydroxide and 424 g of calcium oxide, and the temperature was raised to 85 ° C, and the mixture was stirred for 3 hours. The reaction pressure was controlled by continuously feeding the trifluoromethane sulfonyl fluoride gas. The reaction time is 3.5 hours, then the reaction is kept for 3 hours, and then the temperature is lowered to 25 ℃. The reaction liquid is filtered to obtain the product lithium trifluoromethanesulfonate aqueous solution. Lithium trifluoromethanesulfonate
References[1] Patent: CN105693561, 2016, A. Location in patent: Paragraph 0030
Tag:Lithium trifluoromethanesulfonate(33454-82-9) Related Product Information
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